Adsorption of selected GHG on metal-organic frameworks in the context of accompanying thermal effects

• Autorzy: Gajda Aleksandra , Jodłowski Przemysław , Kozieł Katarzyna , Kurowski Grzegorz , Hyjek Kornelia , Skoczylas Norbert , Pajdak Anna

Identyfikatory

DOI

10.24425/aep.2024.152895

Warianty tytułu

PL

Adsorpcja wybranych gazów cieplarnianych na związkach metaloorganicznych MOF w kontekście towarzyszących jej efektów cieplnych

• Języki publikacji: EN

Abstrakty

EN

Thermal effects accompanying gas sorption on micro- and mesoporous materials provide unique insights into the type, course, and efficiency of sorption. In this study, metal-organic frameworks (MOFs) with different topologies and chemical structures were synthesized and investigated: HKUST-1, Ni-MOF-74, UiO-66, and MIL-140A. These MOFs were characterized structurally and sorptively with respect to selected greenhouse gases (GHGs). Sorption capacities for CO₂ and CH₄ were determined at several temperatures and measurement pressures, and the maximum sorption capacity was determined using the Langmuir-Freundlich model. Thermal effects accompanying adsorption were quantified through the isosteric heat of adsorption parameter. For each MOF, the values of isosteric heat of adsorption were higher for CO₂ than for CH₄. The values of this parameter was determined in the following order: HKUST-1 > Ni-MOF-74 > UiO-66 > MIL-140A. Energy homogeneity of the adsorbent surface was observed in nearly all cases, except for UiO-66 during CO₂ adsorption. Changes in the determined isosteric heat of adsorption of CO₂ with increasing sorption capacity were in the range of 5-15 kJ/mol, while for CH₄ they ranged from 1.4 to 17 kJ/mol, respectively. The level of thermal selectivity of CO₂ over CH₄ was determined in the following order: UiO-66 (1.9) > Ni-MOF-64 (1.7) > MIL-140A (1.5) > HKUST-1 (1.1).

PL

Efekty termiczne towarzyszące sorpcji gazu na materiałach mikro- i mezoporowatych dostarczają unikalnych spostrzeżeń na temat rodzaju, przebiegu i efektywności sorpcji. W niniejszym artykule zsyntetyzowano i zbadano związki metaloorganiczne (MOF) o skrajnie różnej topografii i budowie chemicznej: HKUST-1, Ni-MOF-74, UiO-66 i MIL-140A. MOFy te scharakteryzowano strukturalnie i sorpcyjnie względem wybranych GHG. Określono pojemności sorpcyjne względem CO₂ i CH₄ w kilku temperaturach i ciśnieniach pomiaru oraz określono maksymalną pojemność sorpcyjną zgodnie z modelem Langmuira-Freundlicha. Wyznaczono efekty cieplne towarzyszące adsorpcji poprzez parametr izosterycznego ciepła sorpcji. Dla każdego z MOFów wartości izosterycznego ciepła adsorpcji były wyższe względem CO₂, niż względem CH₄. Wartości tego parametru określono w następującej kolejności: HKUST-1 > Ni-MOF-74 > UiO-66 > MIL-140A. W prawie każdym przypadku zaobserwowano jednorodność energetyczną powierzchni adsorbentu, poza UiO-66 podczas adsorpcji CO₂. Zmiany wyznaczonego izosterycznego ciepła sorpcji CO₂ wraz ze wzrostem pojemności sorpcyjnej były w zakresie 5-15 kJ/mol, natomiast względem CH₄ wyniosły odpowiednio 1.4-17 kJ/mol. Określono poziom selektywności cieplnej CO₂ względem CH₄. Najwyższą selektywność posiadały UiO-66 (1.9) oraz Ni-MOF-74 (1.7), natomiast najniższą MIL-140A (1.5) i HKUST-1 (1.1).

Słowa kluczowe

EN

metal-organic frameworks; CO2 and CH4 adsorption; isosteric heat of adsorption; thermal selectivity

PL

struktury metaloorganiczne; adsorpcja CO2; adsorpcja CH4; efekt cieplny adsorpcji; izosteryczne ciepło sorpcji

• Wydawca: Institute of Environmental Engineering, Polish Academy of Sciences
• Czasopismo: Archives of Environmental Protection
• Rocznik: 2024
• Tom: Vol. 50, no. 4
• Strony: 51--63
• Opis fizyczny: Bibliogr. 69 poz., rys., tab.

Twórcy

autor

Gajda Aleksandra

• Strata Mechanics Research Institute of the Polish Academy of Sciences, Kraków, Poland

• https://orcid.org/0000-0001-7641-5446

autor

Jodłowski Przemysław

• Faculty of Chemical Engineering and Technology, Cracow University of Technology, Kraków, Poland

autor

Kozieł Katarzyna

• Strata Mechanics Research Institute of the Polish Academy of Sciences, Kraków, Poland

• https://orcid.org/0000-0002-1913-4450

autor

Kurowski Grzegorz

• Faculty of Chemical Engineering and Technology, Cracow University of Technology, Kraków, Poland

autor

Hyjek Kornelia

• Faculty of Chemical Engineering and Technology, Cracow University of Technology, Kraków, Poland

autor

Skoczylas Norbert

• AGH University of Krakow, Faculty of Geology, Geophysics and Environmental Protection, Kraków, Poland

• https://orcid.org/0000-0003-1933-2374

autor

Pajdak Anna

• AGH University of Krakow, Faculty of Geology, Geophysics and Environmental Protection, Kraków, Poland

• https://orcid.org/0000-0003-4390-4256

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr POPUL/SP/0154/2024/02 w ramach programu "Społeczna odpowiedzialność nauki II" - moduł: Popularyzacja nauki (2025).