Wytwarzanie i charakteryzowanie membran do przemysłowego rozdzielania mieszanin gazowych oraz modelowanie wybranych procesów prowadzonych z ich udziałem

Szwast, M.

Artykuł - szczegóły

Tytuł artykułu

Wytwarzanie i charakteryzowanie membran do przemysłowego rozdzielania mieszanin gazowych oraz modelowanie wybranych procesów prowadzonych z ich udziałem

Autorzy

Szwast M.

Identyfikatory

Warianty tytułu

Manufacturing and characterization of membranes for industrial gas separation and modeling of selected processes conducted with such membranes

Języki publikacji

Abstrakty

Monografia jest poświęcona membranowemu rozdzielaniu mieszanin gazowych. Podsumowuje prace badawcze autora związane z wytwarzaniem nowych polimerowych membran nieporowatych do realizacji przemysłowych procesów rozdzielania mieszanin gazowych. Zawiera również wyniki prac autora związane z modelowaniem matematycznym wybranych procesów prowadzonych z udziałem takich membran. Autor dokonał krytycznego przeglądu literatury związanej z procesami membranowego rozdzielania mieszanin gazowych i wskazał na istotną rolę inżynierii chemicznej i procesowej w opisie tych procesów. Praca przedstawia wyniki badań podstawowych i rezultaty prac rozwojowych, prowadzące autora do opracowania technologii powtarzalnego wytwarzania nieporowatych membran o zadanych właściwościach i mogących znaleźć bezpośrednie zastosowanie w procesach przemysłowych. W monografii przedstawiono wyniki badań prowadzonych z wykorzystaniem membran własnych, zarówno podczas badań z udziałem czystych gazów, czyli mających na celu wyznaczenie podstawowych właściwości permeacyjnych membran, jak i badań z udziałem mieszanin gazów. Wyniki badań doświadczalnych nad rozdzielaniem mieszanin prowadzonych w module membranowym z trzema króćcami zostały następnie porównane z wynikami numerycznymi uzyskanymi przy pomocy własnego modelu matematycznego. Uzyskano bardzo dobrą zgodność wyników doświadczalnych i modelowych. Autor zaproponował również nowy model matematyczny membranowego procesu rozdzielania mieszanin gazów, prowadzonego w obecności gazu nośnego odbierającego permeat w module membranowym z czterema króćcami. Model ten wyróżnia się spośród znanych w literaturze modeli matematycznych tym, że uwzględnia przekazywanie części energii, jaką posiada strumień gazu płynący konkretną przestrzenią modułu membranowego, strumieniowi gazu przenikającemu przez membranę i wnikającemu do tej przestrzeni. Praca przedstawia sformułowanie modelu i jego interpretację numeryczną.

The monograph is devoted to membrane gas separation. It summarizes the Author's research on the manufacturing of new nonporous polymeric membranes for industrial gas mixtures separation. It also includes the Author's results related to the mathematical modeling of selected membrane gas separation processes that use such membranes. The Author has made a critical review of the literature related to the membrane gas separation processes and pointed to the important role of chemical and process engineering in the description of these processes. The monograph presents the results of basic research and development works, which have led the Author to develop the technology of reproducible production of nonporous membranes that have given, properties and that can be directly used in industrial processes. The monograph presents the results of research conducted using the Author's own membranes, both during research involving pure gases, whose aim has been to determine the membrane basic permeation properties, as well as research involving gas mixtures. The experimental results of the gas mixtures separation carried out in the membrane module with three ports have been compared with the numerical results obtained using the Author's own mathematical model of membrane gas separation process in the membrane module with three ports. A very good agreement between the experimental results and the model ones has been achieved. The Author has also proposed a new mathematical model of membrane gas separation process carried out in the presence of a sweep gas receiving the permeate in the membrane module with four ports. This model is distinguished from other models known in the literature as it takes into account the energy transfer from the gas stream flowing along a specific channel of the membrane module to the gas stream passing through the membrane and penetrating this channel. The monograph presents the formulation of this mathematical model and its numerical interpretation.

Słowa kluczowe

membrany rozdzielanie gazów wytwarzanie membran charakterystyka membrany modelowanie matematyczne

membranes gas separation membrane manufacturing membrane characterization mathematical modeling

Wydawca

Oficyna Wydawnicza Politechniki Warszawskiej

Czasopismo

Prace Wydziału Inżynierii Chemicznej i Procesowej Politechniki Warszawskiej

Rocznik

2017

Tom

Vol. 39, z. 1

Strony

3--133

Opis fizyczny

Bibliogr. 98 poz.., rys., tab., wykr.

Twórcy

autor

Szwast M.

Wydział Inżynierii Chemicznej i Procesowej

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bwmeta1.element.baztech-0214cf41-284b-47b7-9006-ce029a85ff1e