Investigation of Metal Oxides as Catalysts for the Thermal Decomposition of Potassium Chlorate(VII)

• Autorzy: Wojewódka A. , Zakusylo R. , Kravets V. , Romanchenko A. , Jarosz T.

Identyfikatory

DOI

10.22211/cejem/89868

• Języki publikacji: EN

Abstrakty

EN

The results of studies on the thermal decomposition of potassium chlorate(VII) (PP) and the catalytic effects of copper, iron, nickel, titanium, magnesium, chromium and manganese oxides on the process are presented in this paper. The investigated oxides are ranked according to the magnitude of their catalytic effect; of these, CuO and МnО2 show the best catalytic performance. These oxides reduce the PP decomposition temperature from 919.3 K down to even 825.2 K. The share of the catalytic additive in the composition, required to achieve a desirable thermal decomposition profile, was found to be no more than 0.5 wt.%. The activation energy of the decomposition process was determined, using the modified Freeman and Carroll method for both neat PP and PP supplemented with MnO2; the addition of the catalyst produced a 48.8% decrease in the activation energy of thermal decomposition.

Słowa kluczowe

EN

metal oxide catalysts; thermal decomposition; potassium perchlorate; manganese oxide; copper oxide; differential thermal analysis

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2018
• Tom: Vol. 15, no. 2
• Strony: 327--338
• Opis fizyczny: Bibliogr. 13 poz., rys., tab.

Twórcy

autor

Wojewódka A.

• Silesian University of Technology, ks. M. Strzody 7, 44-100 Gliwice, Poland

autor

Zakusylo R.

• Silesian University of Technology, ks. M. Strzody 7, 44-100 Gliwice, Poland

autor

Kravets V.

• Silesian University of Technology, ks. M. Strzody 7, 44-100 Gliwice, Poland

autor

Romanchenko A.

• Silesian University of Technology, ks. M. Strzody 7, 44-100 Gliwice, Poland

autor

Jarosz T.

• Silesian University of Technology, ks. M. Strzody 7, 44-100 Gliwice, Poland

Bibliografia

• [1] Silin, N. A. Oxidants of the Heterogeneous Condensed Systems (original Russian title: Okyslytely geterogenych kondensyrovanych system). Engineer, Moscow 1978, p. 456.
• [2] Zakusylo, V. R.; Zheltonozhko, A. A.; Zakusylo, R. V.; Boyko, L. V.; Uzzhina, L. N.; Margaryan, A. Z. Researches of Development Explosive Charges for Breaking of a Unitized Stone and Technology of Their Manufacturing. Transactions of the Kremenchug State Polytechnic University (Ukraine) 2005, 5(34): 88-90.
• [3] Zakusylo, V. R.; Romanchenko, A. M. Low-speed Charges for Blasting of Block Stone. Collection of Scientific Works of the Eurasian Union of Scientists 2014, 8(16): 144-147.
• [4] Zakusylo, V.; Romanchenko, A.; Zakusylo, R. Influence of Catalysts on the Thermal Decomposition of Potassium Chlorate(VII) and Explosive Characteristics of Composition Based on It. Transactions of the Kremenchug Mikhail Ostrohradskyi National University 2013, 5(82): 103-107.
• [5] Zakusylo, V. R.; Efymenko, A. A.; Romanchenko, A. N. Explosive Composition. Patent U 68559 (Ukraine MPK6 C 06 B 31/28, No. 201112120, Bulletin No. 6) 2012.
• [6] Ping, C.; Li, F.; Jian, Z.; Wei, J. Preparation of Cu/CNT Composite Particles and Catalytic Performance on Thermal Decomposition of Ammonium Perchlorate. Propellants Explos. Pyrotech. 2006, 31: 452-455.
• [7] Patil, P.; Krishnamurthy, V.; Joshi, S. Effect of Nano‐Copper Oxide and Copper Chromite on the Thermal Decomposition of Ammonium Perchlorate. Propellants Explos. Pyrotech. 2008, 33: 266-270.
• [8] Zhang, Y.; Kshirsagar, G.; Ellison, J. E.; Cannon, J. C. Catalytic Effects of Metal Oxides on the Decomposition of Potassium Perchlorate. Thermochim. Acta 1996, 278: 119-127.
• [9] Lee, J.-S.; Hsua, Ch.-K. The DSC Studies on the Phase Transition, Decomposition and Melting of Potassium Chlorate(VII) with Additives. Thermochim. Acta 2001, 367-370.
• [10] Shatalova, T. B.; Shlyachtin, O. A.; Veryaeva, E. S. Methods of Thermal Analysis. (original Russian title: Metody termicheskogo analiza) Moscow State University of M.V. Lomonosov, Moscow 2011, p. 72.
• [11] Zakusylo, V.; Romanchenko, A. Potassium Perchlorate − the Component of the Low-Speed Explosive Composition. Metallurgical Mining Industry 2014, 6: 64-70.
• [12] Petruk, I. P.; Gajdadyn, A. N.; Ephremova, S. A. Methodical Instructions on the Determination of Kinetic Parameters of Thermal Decomposition of Polymeric Materials According to Dynamic Thermogravimetry. (original Russian title: Opredelenie kineticheskih parametrov termodestrukcii polimernych materialov po dannym dinamicheskoy termogravimetrii) VolgSTU, Volgograd 2010.
• [13] Uendlandt, U. Thermochemical Analysis Methods. (original Russian title:Termicheskie metody analiza) Mir, Moscow 1978, p. 527.

Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).