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Development of hydrogen-enriched water gas production technology by processing Ekibastuz coal with technogenic waste

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In the dumps of metallurgical enterprises of Kazakhstan about 700 million tons of waste products are generated annually, and are polluting the atmosphere and the soil. The concentration of valuable components in waste products are no lower than in natural resources. The reserves of coal in the Ekibastuz basin are estimated to be more than a billion tons, and almost half of this is made up of ash. Every year, up to 30 million tons of ash-cinder waste is generated, which presents a serious threat to nature. Gallium and germanium concentrations in dumps are approximately 200 grams per ton, which is comparable to the content in coal before processing. The current research aims at creating a unit to obtain hydrogen-enriched water gas from Ekibastuz coal, with the production of zinc, gallium and germanium sublimates, copper-containing cast iron, slag wool and cast stone, through the joint processing of zinc-rich slag and ash-cinder wastes from thermal power plants. To achieve this, we used previous methods of extreme energy saving and a new method, the smelt layer with inversion phase. Experimental results from the “reactor inversion phase – rotary kiln” (RIPh) unit, which processed zinc-germanium contained slag, showed the potential to extract germanium from zinc sublimates, to reduce iron to the form of cupreous cast iron, and to obtain combustible gases and smelt suitable for slag-wool production. Calculations performed on the joint processing of Ekibastuz coal and zinc-rich slag using the proposed unit“ reactor of inversion phase–rotary kiln–gas generator” showed it can obtain hydrogen-enriched watergas, along with the extraction of valuable components of primary raw material.
Rocznik
Strony
221--231
Opis fizyczny
Bibliogr. 28 poz., rys., tab.
Twórcy
  • Energy Department, S. Seifullin Kazakh Agrotechnical University, Astana, Republic of Kasakhstan
  • Energy Department, S. Seifullin Kazakh Agrotechnical University, Astana, Republic of Kasakhstan
autor
  • Energy Department, S. Seifullin Kazakh Agrotechnical University, Astana, Republic of Kasakhstan
autor
  • Faculty of Power and Aeronautical Engineering, Warsaw University of Technology, Warsaw Poland
Bibliografia
  • [1] S.Zh. Daukaev. Mineral resources of Kazakhstan – Possibility of scientific and technical progress, Proceedings of 1st International Conference on Problems of Complex Processing of Raw Materials of Kazakhstan, Almaty, p.11.2003. (in Russian).
  • [2] A.A. Zharmenov. Republican State Enterprise “National Center on Complex Treatment of Mineral Raw Materials of RK” – Into the future with optimism, Proceedings of 1st International Conference on Problems of Complex Processing of Raw Materials of Kazakhstan, Almaty, p. 4, 2003. (in Russian).
  • [3] I.A. Blide, L.I. Slyusarenko, and Z. Abisheva. The ash-cinder wastes of power industry – the raw material to produce rare metals and alumina, Complex Using of Mineral Raw Materials, 4:39–51, 2008. (in Russian).
  • [4] B.B. Kenzhaliev, A.N. Berkinbayeva, and E.N. Suleimenov. Use of conjoint reactions for extraction of metals from mineral raw materials, European Scientific Journal, 10(6):147–155, 2014.
  • [5] A.N. Alekhanovich and V.V. Bogomolov. Composition and slagging properties of ash of ekibastuz coal, Power Engineering, 5:29–31, 1999. (in Russian).
  • [6] V.A. Sergeev, Yu.F. Sergeeva, S.V. Mamyachenkov, O.S. Anisimova, and S.V. Karelov. Processing of technogenic lead-containing intermediates using complexing agent solutions, Metallurgist, 57(1–2):80–82, 2013. doi:10.1007/s11015-013-9694-0.
  • [7] A.K. Koizhanova, L.L. Osipovskaya, and M.B. Erdenova. Study of precious metals extraction recovery from technogenic wastes, In: Proceedings of 12th International Multidisciplinary Scientific GeoConference–SGEM2012, vol.1, pp. 843–846, June 2012.
  • [8] J.L. Michailov. Physico-chemical studies of microcomponents leaching from ash of coal combustion of ekibastuz basin, Abstract of Ph.D. Thesis. Omsk, 2008. (in Russian).
  • [9] V.A. Chanturiya, I.V. Shadrunova, N.N. Orekhova, and N.L. Chalkova. Technology of zinc recovery from mine and waste dump water, Obogashchenie Rud (Mineral processing), 1:35– 39, 2011 (in Russian).
  • [10] M. Borell. Slag – A Resourse in the Sustainable Society., In: Proceedings of International Conference on Mining and the Environment, Metals and Energy Recovery “Securing the future”, pp.130–138, Skellefteå, Sweden, 27 June–1 July, 2005.
  • [11] L.N. Sidelkovskiy and A.P. Shurigin. Cyclone Energy-technological Processes, Metallurgizdat, Moscow 1983. (in Russian).
  • [12] K. Badyda, P. Krawczyk, and K. Pikoń. Relative environmental footprint of waste-based fuel burned in a power boiler in the context of end-of-waste criteria assigned to the fuel, Energy, 100:425–430, 2016. doi:10.1016/j.energy.2016.02.024.
  • [13] A. Grzebielec, A. Rusowicz, and A. Szelągowski. Air purification in industrial plants producing automotive rubber components in terms of energy efficiency, Open Engineering, 7(1):106–114, 2017. doi:10.1515/eng-2017-0015.
  • [14] A.D. Klyuchnikov. Method of extreme energy saving as methodological basis for formation of energy-material saving and ecologically perfect heat technological systems, Set of scientific works, Moscow, Energy Institute, 105:3–7,1986. (in Russian).
  • [15] B. Dikhanbayev. Experimental and calculation prediction of fuel consumption on unit based on reactor inversion phase processing zinc-containing slag, Industry of Kazakhstan, 6:79–81, 2006.(in Russian).
  • [16] B. Dikhanbayev, A. Dikhanbayev, and K. Baubekov. Calculated estimation of fuel consumption on processing plant of zinc-containing slag based on reactor of phase inversion, In: Proceedings of Eurasian Multidisciplinary Forum, pp. 124–133, Tbilisi, 2013.
  • [17] B. Dikhanbayev and A. Dikhanbayev. Calculated and experimental evaluation of efficiency of chemical regeneration waste gases., Complex Using of Mineral Raw Materials, Almaty 2(281):111–116, 2012. (in Russian).
  • [18] Heat power engineering and heat technology, Reference manual, Moscow–Energy, 1980. (in Russian).
  • [19] B.I. Dikhanbayev, A.A. Zharmenov, S.A.Telbaev, A.Zh. Terlikbayeva, A.G. Saveliev, and A.B. Dikhanbayev. Processing method of zinc-containing products, Patent(?) No.30040, Kazakhstan, 21.05.2002. (in Russian).
  • [20] B.I. Dikhanbayev, A. Zhumabekova, and A. Rakhmatullina. Processing method of zinc containing slag of shaft smelting. Conclusion about output of innovation patent for an invention, No. 29083 from 23.11.2015. (in Russian).
  • [21] B. Dikhanbayev and A. Dikhanbayev. About pilot plant on processing of excavated zinc containing slag, Complex Using of Mineral Raw Material, Almaty, 4:85–90, 2008. (in Russian).
  • [22] B. Dikhanbayev, A. Zharmenov, and A. Dikhanbayev. Energy-saving reactor for processing excavated slag. Theses of works of international application-oriented scientific conference “Mining and Metallurgy in Kazakhstan. State and Perspectives”, pp. 113–115, Almaty, 2012. (in Russian).
  • [23] B. Dikhanbayev. Elaboration of measures of intensive power saving in the system of lead processing slag fumingation, Abstract of Ph.D. Thesis, Moscow, 1991, pp. 20. (in Russian).
  • [24] B.I. Dikhanbayev and A.B. Dikhanbayev. Smelt layer with inversion phase – high efficiency method of smelt processing, Complex Using of Mineral Raw Materials, Almaty, 2(275):44–51, 2011. (in Russian).
  • [25] B.I. Dikhanbayev and A.B. Dikhanbayev. Results of research on slag processing on reactor inversion phase, In International Application-Oriented Scientific Conference “Problems and prospects of development of mining-metallurgical branch – theory and practice, devoted to 20 years of RGP”, National Centre on Complex Processing of Mineral Raw Material of RK, Karaganda, 2013, pp.87–90. (in Russian).
  • [26] A.B. Dikhanbayev, B.I. Dikhanbayev, M. Moldabaev, and K.T. Baubekov. Development of energy-saving thermal circuitry of excavated slag processing. Materials of 7th International application-oriented scientific conference “Academic science – problems and achievements”, vol.2, pp. 181–190, North Charleston, USA, 2015.
  • [27] B. Dikhanbayev. Creation of pilot plant on energy-saving processing of excavated slag, Collected scientific works of National Research Institute of non-ferrous metals “Gintsvetmet”, 546–553, Moscow, 2008, (in Russian).
  • [28] R.S. Sokolov. Chemical Engineering, Vol. 2. Moscow. Vlados, 2013. (in Russian).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-017de48e-65fc-4eee-a474-aad31cedc3e2
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