Adsorption of Iron and Manganese Ions from Mine Acid Water Using Manganese Green Sand in Batch Process

• Autorzy: Kusdarini Esthi , Sania Putri Rizka , Budianto Agus

Identyfikatory

DOI

10.12911/22998993/173007

• Języki publikacji: EN

Abstrakty

EN

Fe and Mn metal ions in acid mine drainage can contaminate water bodies and soil, endangering human health. In this study, the adsorption of Fe and Mn in acid mine drainage was carried out using manganese greensand. This study aimed to obtain 1) the adsorption model of Fe and Mn isotherms using manganese greensand and 2) the surface morphology of manganese greensand before and after the adsorption process. This study used laboratory-scale experimental methods with variable concentrations of Fe (325, 400, 475, 550, 625 mg/L) and Mn (432, 507, 582, 657, 732 mg/L). The Freundlich and Langmuir adsorption isotherm models were used to determine the adsorption capacity of Fe and Mn by manganese greensand. Test for Fe and Mn content using the AAS method and test the surface morphology and content of manganese greensand using SEM-EDX. The results showed that: (1) the Freundlich equation test yielded for Fe: in a constant R² of 0.9862, n = 0.6912, KB = 0.2180 mg/g, while the Langmuir equation test yielded in a constant R² of 0.8836, b = 0.0051 L/mg, q_m = 169.4915 mg/g; the Freundlich equation test yielded for Mn: in a constant R² of 0.9923, n = 0.8651, KB = 1.0445 mg/g, while the Langmuir equation test yielded in a constant R² of 0.6615, b = 0.0010 L/mg, q_m = 500 mg/g; (2) The surface morphology of manganese greensand before contact with acid mine drainage contains needle-shaped particles of uniform size with a hexagonal structure, whereas, after contact with acid mine drainage, the particles are clumped like cotton and form needles with varying sizes.

Słowa kluczowe

EN

adsorption; batch process; iron; manganese greensand; mine acid water

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2023
• Tom: Vol. 24, nr 12
• Strony: 158--166
• Opis fizyczny: Bibliogr. 25 poz., rys., tab.

Twórcy

autor

Kusdarini Esthi

• Mining Engineering Department, Adhi Tama Institute of Technology Surabaya, Jl. Arief Rachman Hakim 100 Surabaya 60117, Indonesia

• https://orcid.org/0000-0002-7719-5614

autor

Sania Putri Rizka

• Mining Engineering Department, Adhi Tama Institute of Technology Surabaya, Jl. Arief Rachman Hakim 100 Surabaya 60117, Indonesia

autor

Budianto Agus

• Chemical Engineering Department, Adhi Tama Institute of Technology Surabaya, Jl. Arief Rachman Hakim 100 Surabaya 60117, Indonesia

• https://orcid.org/0000-0003-1758-9707

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).