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Fluorescence properties of mechanically dispersed crude oil

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EN
Abstrakty
EN
Despite of numerous actions undertook by the global and local authorities towards protection of marine environment, oil pollution loads into the Baltic Sea still tend to increase and need to be continuously estimated in order to apply the legal regulations. There is a demand for multifarious studies on the environmental effects of oil products. Dispersed oil droplets occur in seawater as the result of contaminated river inflows, bilge water discharges and as the consequence of mechanical and chemical dispersion of oil spills. Their optical properties depend on oil type, concentration and size distribution. Oil content influences many environmental factors, like water quality and bio-optical parameters (e.g. water-leaving radiance, inherent optical properties, seawater fluorescence). We present a unique study of the collected database of crude oil fluorescence spectra for better understanding the correlations between oil optical properties and its concentration, as well as for evaluation of the oil droplets size by the application of vacuum filtering using three filters of different permeability. Fluorescence spectra have been registered for oil-in-water emulsion samples prepared in the laboratory by mechanical dispersion. We discuss the optical properties of crude oil and the relationships between them in the context of potential remote detection of dispersed oil in seawater.
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autor
  • Gdynia Maritime University Faculty of Marine Engineering Morska Street 81-87, 81-225 Gdynia, Poland tel.: +48 58 6901588, +48 58 6901384; fax: +48 58 6901399
autor
  • Gdynia Maritime University Faculty of Marine Engineering Morska Street 81-87, 81-225 Gdynia, Poland tel.: +48 58 6901588, +48 58 6901384; fax: +48 58 6901399
Bibliografia
  • [1] American Petroleum Institute (API), http://www.api.org/
  • [2] Baszanowska, E., Otremba, Z., Spectroscopic methods in application to oil pollution detection in the sea, Journal of KONES Powertrain and Transport, Vol. 19, No. 1, pp. 15-20, 2012.
  • [3] Baszanowska, E., Otremba, Z., Toczek, H., Rohde, P., Fluorescence spectra of oil after it contacts with aquatic environment, Journal of KONES Powertrain and Transport, Vol. 20, No. 3, pp. 29-34, 2013.
  • [4] Conmy, R. N., et al., Submersible optical sensors exposed to chemically-dispersed crude oil: wave tank simulations for improved oil spill monitoring, Environmental Science & Technology, No. 12, pp. 1803-1810, 2013.
  • [5] Haule, K., Toczek, H., Optical properties of crude oil detected in seawater, Journal of KONES Powertrain and Transport (in press), 2014.
  • [6] HELCOM, Baltic Sea Environment Proceedings, No.123, 2010.
  • [7] HELCOM, Third Periodic Assessment of the State of the Marine Environment of the Baltic Sea (1989-1993), 1996.
  • [8] Rudź, K. Toczek, H.,Estimation of emulsified and dissolved oil content in seawater, Journal of KONES Powertrain and Transport, Vol. 20, No. 1, pp. 287-293, 2013.
  • [9] Stelmaszewski, A., Determination of petroleum pollutants in coastal waters of the Gulf of Gdansk, Oceanologia, No. 51(1), pp. 85-92, 2009.
  • [10] Stelmaszewski, A., Fluorescence method for determination of oil identity, Optica Appl., XXXIV (3), 2004.
  • [11] United States Environmental Protection Agency (EPA), http://www.epa.gov/
  • [12] Zhao, L., et al., Evolution of droplets in subsea oil and gas blowouts: Development and validation of the numerical model VDROP-J, Marine Pollution Bulletin (in press), 2014.
  • [13] Zielinski, O., Busch, J. A., Cembella, A. D., Daly, K. L., Engelbrektsson, J., Hannides, A. K., Schmidt, H., Detecting Marine Hazardous Substances and Organisms: Sensors for Pollutants, Toxins and Pathogens, Ocean Science, Vol. 5, pp. 329-349, 2009.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-008c53ff-3b67-48ee-b32f-42aa125bc9ff
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