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Composite membranes with poly(ether ether ketone) as support and polyaniline like structure, with potential applications in fuel cells

100%

Baicea C. , Luntraru V. , Vaireanu D. , Vasile E. , Trusca R.

Open Chemistry

2013

tom 11

nr 3

438-445

Abstract In this paper we present the synthesis of two composite membranes with sulfonated polyether etherketone as support polymer and as conductive polymers: polyaniline and poly(p-phenylenediamine) - which has a similar structure with polyaniline. The support membranes were obtained by the phase inversion process, the conductive polymers were added by in situ polymerization into the membrane pores, and to increase the conductive properties they were doped with polystyrene sulfonic acid. The synthesized membranes were characterized by FT-IR spectroscopy, SEM, EDAX and electrochemical impedance spectroscopy. Graphical abstract [...]

Investigation of electrical properties of PANI/chalcogenide junctions

86%

Shaktawat V. , Patidar D. , Sharma K. , Saxena N. , Sharma T.

Open Chemistry

2009

tom 7

nr 4

769-773

Pure Polyaniline (EB) and Polyaniline doped with different protonic acids (ESs) were chemically synthesized using ammonium peroxydisulphate (APS) as an oxidant. Junctions have been prepared by evaporating chalcogenide materials (ZnSe, CdSe) on conducting polyaniline (EB & ESs) pellets using a vacuum evaporation technique. I–V characteristics of junctions have been studied at room temperature using the Keithley electrometer 6517A. I–V measurements show the rectification effect. A junction of ES[PO43−] may be preferred over the other junctions due to its low ideality factor and maximum rectification ratio. [...]

Development of Smart Nanocontainers With A Zinc Phosphate Core and A pH-Responsive Shell for Controlled Release of Immidazole

86%

Jadhav A. J. , Karekar S. E. , Pinjari D. V. , Datar Y. G. , Bhanvase B. A. , Sonawane S. H. , Pandit A. B.

Hybrid Materials

2015

tom 2

nr 1

A simple and flexible method has been developed to fabricate reversibly switchable nanocontainers (by layer by layer assembly) using zinc phosphate (ZP) nanoparticles as a core material and subsequent deposition of oppositely charged species of polyelectrolyte (polyaniline and polyacrylic acid) and organic corrosion inhibitor (immidazole). Immidazole was entrapped between polyaniline (PANI) and polyacrylic acid (PAA). The PAA nanovalve can control the access of immidazole molecules to and from the nanocontainers. The average particle size of the synthesized nanocontainer was found to be in the range of 250–500 nm. X-ray diffraction (XRD), particle size analysis (PSA), zeta potential, and fourier transform infrared spectroscopy (FTIR) analysis confirms the successful formation of the layered structure of nanocontainers. UV-vis spectroscopy was used to analyze the release rate of immidazole in media of different pH as a function of time. This core-shell nanostructure can have potential applications in corrosion inhibition paint formulation.