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Acylation of aromatic compounds by acid anhydrides using Preyssler's anion [NaP5W30O110]14-and heteropolyacids as green catalysts

100%

Gharib A. , Jahangir M. , Scheeren J.

Polish Journal of Chemical Technology

2011

tom 13

nr 2

11-17

The Preyssler, Wells-Dowson and Keggin heteropolyacids are efficient and eco-friendly solid acid catalysts for the acylation of electron-rich aromatic compounds with acid anhydrides. The performance of different forms of heteropolyacids was compared. In all the cases, the best results were obtained using the Preyssler heteropolyacid as the catalyst. In the presence of 25 mol% (with respect to H+ equivalency) Preyssler catalyst, highly para-selective acetylation of anisole occurs using two equivalents of acetic anhydride, in 15 min at room temperature. The isolated yield of the p-methoxyacetophenone product is 98%.

P-Acylphosphonium salts and their vinyloges - application in synthesis

100%

Kolesinska B.

Open Chemistry

2010

tom 8

nr 6

1147-1171

Review with 101 refs. of progress in synthetic applications and properties of P-acylphosphonium salts including acylation via P-acylphosphonium salts, enantioselective acylation using chiral phosphine ligands, nucleophilic (β)-oniovinylation, and reaction involving vinyloges of P-acylphosphonium salts formed by treatment conjugated alkenoates or alkynoates with phosphines.