Dipole Moment, Molar Kerr Constant, Crystal and Molecular Structure of 3-Chloro-N-methyl-N-nitroaniline

• Autorzy: Prezhdo, V.
• Języki publikacji: EN

Abstrakty

EN

Dipole moment, molar Kerr constant, crystal and molecular structure of m- ClC6H4N(CH3)NO2 (or C7H7ClN2O2) are studied. Comparison the data obtained by dipole moment and molar Kerr constant measurement, X-ray crystallographic investigation and quantum-chemical calculation show that the molecule contains a planar NNO2 nitroamino group which is twisted around the N-Cphenyl bond by ca 61.4_ from the plane of the aromatic ring. The structural data are compared with the data for p- ClC6H4N(CH3)NO2 and the influence of the substituent on the structural parameters of the molecule is established.

Słowa kluczowe

EN

N-nitroamino group; N-methyl-N-nitro-chloranilines; crystal structure; dipole moment; molar Kerr constant; quantum chemical calculation

• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2001
• Tom: Vol. 75, nr 5
• Strony: 707-718

Twórcy

autor

Prezhdo, V.

• Institute of Chemistry, Pedagogical University, Checińska 5, 25-020 Kielce, Poland