Synthesis and Reactions of Organic Compounds with a Nitrogen Atom. Part XVII. Reactions of Acyclic and Monocyclic Chlorides with Phenylselenosodium

• Autorzy: Bąkowska-Janiszewska, J.
• Języki publikacji: EN

Abstrakty

EN

The reaction of neryl (3), geranyl (4), (+)-carvotanacetyl (5), (-)-carvyl (6) and perillyl (7) chlorides with phenylseleno- (1) or phenyltellurosodium (2), and then with chloramine- T afforded _,_-unsaturated toluenesulfonamides 8-11, which were reduced with sodium in liquid ammonia to allylic amines 12-15. Allylic phenyltellurides were oxidized by air to carbonyl compounds 29-31 or alcohol 28.

Słowa kluczowe

EN

phenyltellurides; phenylselenides; toluenesulfonamides; allylic amines

• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2001
• Tom: Vol. 75, nr 5
• Strony: 649-656

Twórcy

autor

Bąkowska-Janiszewska, J.

• Faculty of Chemistry, Nicolaus Copernicus University, 87-100 Torun, Poland