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2017 | Vol. 43, nr 1 | 31--47
Tytuł artykułu

Advanced oxidation treatment of pentoxifylline in aqueous solutions

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The degradation of pentoxifylline (PTX) using H2O2, UV, H2O2/UV, Fenton and photo-Fenton processes has been examined in aqueous solutions. The influence of oxidation agent and initial PTX concentration, on H2O2, H2O2/UV, Fenton and photo-Fenton reactions was investigated. The addition of inorganic ions (Cl, NO3, SO42– and CO32–) on the degradation efficiency of PTX was tested for H2O2/UV, Fenton and photo-Fenton processeses. The results indicate that the photo-Fenton reaction is the most sufficient for PTX removal. The complete pharmaceutics decomposition is achieved after 5 min under optimized concentration of FeSO4,·7 H2O2 and H2O2. The degradation of PTX is inhibited in the presence of inorganic matter in H2O2/UV and Fenton reaction. In the photo-Fenton process addition of above compounds does not affect the reaction rate. Structures of ten products of photo-Fenton reaction have been proposed.
Wydawca

Rocznik
Strony
31--47
Opis fizyczny
Bibliogr. 24 poz., tab., rys.
Twórcy
  • Department of Chemistry and Technology of Functional Materials, Gdańsk University of Technology, ul. Narutowicza 11/12, 80-233 Gdańsk, Poland, beatakaminska.gda@wp.pl
  • Department of Chemistry and Technology of Functional Materials, Gdańsk University of Technology, ul. Narutowicza 11/12, 80-233 Gdańsk, Poland
  • Department of Pharmaceutical Technology and Biochemistry, Gdańsk University of Technology, ul. Narutowicza 11/12, 80-233 Gdańsk, Poland
  • Aquateam COWI AS Hasleveien 10, 0571 Oslo
autor
  • Department of Chemistry and Technology of Functional Materials, Gdańsk University of Technology, ul. Narutowicza 11/12, 80-233 Gdańsk, Poland
autor
  • Department of Chemistry and Technology of Functional Materials, Gdańsk University of Technology, ul. Narutowicza 11/12, 80-233 Gdańsk, Poland
Bibliografia
  • [1] BLAIR B.D., CRAGO J.P., HEDMAN C.J., KLAPER R.D., Pharmaceuticals and personal care products found in the Great Lakes above concentrations of environmental concern, Chemosphere, 2013, 93, 2116.
  • [2] KLEYWEGT S., PILEGGI V., YANG P., HAO C., ZHAO X.M., ROCKS C., THACH S., CHEUNG P., WHITEHEAD B., Pharmaceuticals, hormones and bisphenol A in untreated source and finished drinking water in Ontario, Canada occurrence and treatment efficiency, Sci. Total. Environ., 2011, 409, 1481.
  • [3] WENG C.H., LIN Y.T., LIU N., YANG H.Y., Enhancement of the advanced Fenton process by ultrasound for decolorisation of real textile wastewater, Color. Technol., 2014, 130, 133.
  • [4] AKMEHMET BALCIOGLU I., ÖTKER M., Treatment of pharmaceutical wastewater containing antibiotics by O3 and O3/H2O2 processes, Chemosphere, 2003, 50 (1), 85.
  • [5] ANDREOZZI R., CAMPANELLA L., FRAYSSE B., GARRIC J., GONNELLA A., LO GIUDICE R., MAROTTA R., PINTO G., POLLIO A., Effects of advanced oxidation processes (AOPs) on the toxicity of a mixture of pharmaceuticals, Water Sci. Technol., 2004, 50 (5), 23.
  • [6] KLAMERTH N., RIZZO L., MALATO S., MALDONADO M.I., AGÜERA A., FERNÁNDEZ-ALBA A.R., Degradation of fifteen emerging contaminants at μg·L–1 initial concentrations by mild solar photo-Fenton in MWTP effluents, Water Res., 2010, 44 (2), 545.
  • [7] HUBER M.M., KORHONEN S., TERNES T.A., GONTEN U., Oxidation of pharmaceuticals during water treatment with chlorine dioxide, Water Res., 2005, 39, 3607.
  • [8] SNYDER A.A., WERT E.C., REXING D.J., ZEGERS R.E., DRURY D.D., Ozone oxidation of endocrine disruption and pharmaceuticals in surface water and wastewater, Ozone Sci. Eng., 2006, 28, 445.
  • [9] HEGDE R.N., SHETTI N.P., NANDIBEWOOR A.T., Kinetic and mechanistic investigations of oxidation of pentoxifylline drug by alkaline permanganate, Ind. Eng. Chem. Res., 2009, 48, 7025.
  • [10] ABBAR J.C., MALODE S.J., NANDIBEWOOR S.T., Electrochemical determination of a hemorheologic drug, pentoxifylline at a multi-walled carbon nanotube paste electrode, Bioelectrochem., 2012, 83, 1.
  • [11] ABBAR J.C., MALODE S.J., NANDIBEWOO S.T., Osmium(VIII) catalysed and uncatalyzed oxidation of a hemorheologic drug Pentoxifylline by alkaline cooper(III) periodate complex. A comparative kinetic and mechanistic approach, Polyhedron, 2010, 29, 2875.
  • [12] MAGUREANU M., PIROI D., MANDACHE N.B., DAVID V., MEDVEDOVICI A., PARVULESCU V.I., Degradation of pharmaceutical compound pentoxifylline in water by non-thermal plasma treatment, Water Res., 2010, 44, 3445.
  • [13] MALODE S.J., ABBAR J.C., NANDIBEWOOR S.T., Mechanistic investigations of ruthenium(III) catalyzed oxidation of pentoxifylline by cooper(III) periodate complex in aqueous alkaline medium, Monatsh. Chem., 2011, 142, 469.
  • [14] CHRISTENSEN H.S., SEHESTED H., CORFITZAN H., Reactions of hydroxyl radicals with hydrogen peroxide at ambient and elevated temperatures, J. Phys. Chem., 1982, 86, 15.
  • [15] CHU W., WONG C.C., The photocatalytic degradation of dicamba in TiO2 suspensions with the help of hydrogen peroxide by different near UV irradiations, Water Res., 2003, 38 (4), 1037.
  • [16] VALDERRAME C., ALESSANDRI R., AUNOLA T., CORTINA J.L., GAMISANS X., TUHKANEN T., Oxidation by Fenton’s reagent combined with biological treatment applied to a creosote-contaminated soil, J. Hazard. Mater., 2009, 166, 594.
  • [17] HEREDIA J.B., DOMINNGUEZ J.R., LÓPEZ R., Advanced oxidation of cornprocessing wastewater using Fenton’s reagent: kinetics and stoichiometry, J. Chem. Technol. Biotechnol., 2004, 79, 407.
  • [18] ROZASA O., CONTRERAS D.M., MONDACA A., PEREZ-MOYA M., MANSILLA H.D., Experimental design of Fenton and photo-Fenton reactions for the treatment of ampicillin solutions, J. Hazard. Mater., 2010, 177, 1025.
  • [19] ARSLAN-ALATON I., GURSES F., Photo-Fenton and photo-Fenton-like oxidation of procaine penicillin G formulation effluent, J. Photochem. Photobiol. A Chem., 2004, 165, 165.
  • [20] PEREZ-MOYA M., GRAELLS M., Fenton and photo-Fenton degradation of 2-chlorophenol: ultivariate analysis and toxicity monitoring, Catalysis Today, 2007, 124, 163.
  • [21] TROVÓ A.G., NOGUEIRA R.F.P., Diclofenac abatement using modified solar photo-Fenton process with ammonium iron(III) citrate, J. Braz. Chem. Soc., 2011, 22, 1033.
  • [22] ZHOU C., GAO N., DENG Y., CHU W., RONG W., ZHOU S., Factors affecting ultraviolet irradiation/hydrogen peroxide (UV/H2O2) degradation of mixed N-nitrosamines in water, J. Hazard. Mater., 2012, 231, 43.
  • [23] MAZELLIER P., BUSSET C., DELMONT A., LAAT J., A comparison of fenuron degradation by hydroxyl and carbonate radicals in aqueous solution, Water Res., 2007, 41, 4585.
  • [24] RIGA A., SOUTSAS K., NTAMPEGLIOTIS K., KARAYANNIS V., PAPAPOLYMEROU G., Effect of system parameters and of inorganic salts on the decolorisation and degradation of procion hexl dyes. Comparison of H2O2/UV, Fenton, UV/Fenton, TiO2/UV and TiO2/ UV/H2O2 processes, Desalination, 2007, 211 (1), 72.
Uwagi
PL
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).
Typ dokumentu
Bibliografia
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Identyfikator YADDA
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