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2015 | Vol. 12, no. 3 | 403--416
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Preparation and Characterization of 1-(5-Azido-1H-1,2,4-triazol-3-yl)tetrazole

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This study presents the preparation of 1-(5-azido-1H-1,2,4-triazol-3yl)tetrazole (5) from commercially available chemicals in a five step synthesis. The energetic title compound was comprehensively characterized by various means, including vibrational (IR, Raman) and multinuclear (1H, 13C, 14N, 15N) NMR spectroscopy, mass spectrometry and differential scanning calorimetry. The sensitivities towards various outer stimuli (impact, friction) were determined according to BAM standards. The enthalpy of formation was calculated at the CBS-4M level of theory.
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Bibliogr. 22 poz., rys., tab.
  • Department of Chemistry, Ludwig-Maximilian University of Munich, Butenandstr. 5-13 (D), 81377 Munich, Germany
  • Department of Chemistry, Ludwig-Maximilian University of Munich, Butenandstr. 5-13 (D), 81377 Munich, Germany,
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