The effect of calcination temperature on properties and activity of Cu/ZnO/Al₂O₃catalysts

• Autorzy: P. Kowalik , W. Próchniak
• Języki publikacji: EN

Abstrakty

EN

The paper presents the results of the investigation on the influence of calcination temperature of Cu-Zn-Al catalyst precursor, on physicochemical properties and catalytic activity for water gas shift reaction. A model precursor of chemical composition corresponding with a typical commercial catalyst and prepared by coprecipitation method was studied. It has been shown that the temperature of calcination step determines the surface properties of the final catalyst, the active phase dispersion, and thus significantly affects the catalytic activity.

• Czasopismo: Annales UMCS, Chemia
• Rocznik: 2010
• Tom: 65
• Strony: 79-87

Daty

wydano

2010-01-01

online

2011-01-28

Twórcy

autor

P. Kowalik

• Catalysts Department, Fertilizers Research Institute, Al. Tysiąclecia Państwa Polskiego 13A, 24-110 Pulawy, Poland

autor

W. Próchniak

• Catalysts Department, Fertilizers Research Institute, Al. Tysiąclecia Państwa Polskiego 13A, 24-110 Pulawy, Poland

Bibliografia

• M. V. Twigg; Catalyst Handbook; Wolfe Publishing Ltd 1989.
• M. Behrens, I. Kasatkin, S. Kuhl, G. Weinberg; Chem. Mater., 22, 386 (2010).
• M. J. L. Ginés, N. Amadeo, M. Laborde, C. R. Apesteguía; Appl. Catal. A; 131, 283 (1995).
• S. Kannan, V. Rives, H. Knözinger; J. Solid State Chem.; 177, 319 (2004).
• F. Kovanda, K. Jiratova, J. Rymes, D. Kolousek, Appl. Clay Sci. 18, 71 (2001).
• J. M. Correa Bueno, M. Gazzano, M. Goncalves Coelho, A. Vaccari; Appl Catal. A 103, 69 (1993).
• F. Cavani, F. Trifiro, A. Vaccari; Catal. Tod., 11, 173 (1991).
• M. V. M. Souza, K. A. Ferreira, O. R. de Macedo Neto, N. F. P. Ribeiro, M. Schmal; Cat. Today 133, 750 (2008).
• Y. Fernández, J. A. Menéndez, A. Arenillas, E. Fuente, J. H. Peng, Z. B. Zhang, W. Li, Z. Y. Zhang; Solid State Ionics, 180, 1372 (2009).
• P. Guo, L. Chen, Q. Yang, M. Qiao, H. Li, H. Li, H. Xu, K. Fan, Int. J. Hydr. Energ., 34, 2361 (2009).
• M. Rønning, F. Huber, H. Meland, H. Venvik, D. Chen, A. Holmen; Catal. Today, 100, 249 (2005).
• R. L. Frost, Z. Ding, Thermochimica Acta 390, 167 (2004)
• I. Melián-Cabrera, M. López Granados, J. L. G. Fierro; Phys. Chem. Chem. Phys., 4, 3122 (2002).
• G. J. Millar, I. H. Holm, P. Uwins, J. Drennan, J. Chem. Soc., Faraday Trans. 94, 593 (1998).
• J. Zieliński, React. Kinet. Catal. Lett., 17, 69 (1981).
• G. E. Paris, K. Klier, J. Catal., 97, 374 (1986).
• G. C. Chinchen et al., J. Catal., 103, 79 (1987).
• P. Kowalik, W. Próchniak, T. Borowiecki, Przem. Chem. 86/5, 433 (2007).
• M. Tiomkin, N. Kulkova, Kin. Kat., 10, 461 (1969).

Identyfikatory

DOI

10.2478/v10063-010-0008-0