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2012 | 14 | 4 | 77-82
Tytuł artykułu

Dehydrogenation of propane with CO2– a new green process for propene and synthesis gas production

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Dehydrogenation of propane in the presence of CO2 was considered as an alternative to commercial dehydrogenation pathway of obtaining propene and the new sources of synthesis gas. Based on thermodynamic calculations and a catalytic tests it was shown that by controlling CO2 concentration in the feed the molar ratio of H2/CO (synthesis gas) in the products mixture can be regulated. Several different pathways of DHP-CO2 process integration with commercialized chemical processes utilized synthesis gas were proposed
Wydawca
Rocznik
Tom
14
Numer
4
Strony
77-82
Opis fizyczny
Daty
wydano
2012-12-01
online
2013-01-12
Twórcy
  • Cracow University of Technology, Institute of Organic Chemistry and Technology, ul. Warszawska 24, 31-155 Kraków, Poland , pmichor@pk.edu.pl
  • Cracow University of Technology, Institute of Organic Chemistry and Technology, ul. Warszawska 24, 31-155 Kraków, Poland
  • Cracow University of Technology, Institute of Organic Chemistry and Technology, ul. Warszawska 24, 31-155 Kraków, Poland
  • Cracow University of Technology, Institute of Organic Chemistry and Technology, ul. Warszawska 24, 31-155 Kraków, Poland
Bibliografia
  • 1. Wang, S. & Zhu, Z.H. (2004). Catalytic conversion of alkanes to olefins by carbon dioxide oxidative dehydrogenations a review. Energy Fuels 18(4), 1126-1139. DOI:10.1021/ef0340716.[Crossref]
  • 2. Krylov, O., Mamedov, A. & Mirzabekova, S. (1995). Oxidation of hydrocarbons and alcohols by carbon dioxide on oxide catalysts, Ind. Eng. Chem. Res. 34(2), 474-482. DOI:10.1021/ ie00041a007.[Crossref]
  • 3. Valenzuela, R.X., Bueno, G., Cortés Corberán, V., Xu, Y., Chen, C. (2000). Selective oxidehydrogenation of ethane with CO2 over CeO2-based catalysts. Catal. Today 61(1), 43-48. DOI:10.1016/S0920-5861(00)00366-7.[Crossref]
  • 4. Cavani, F. & Trifirò, F. (1995). Alternative processes for the production of styrene. Appl. Catal. A: General 133(2), 219-239. DOI:10.1016/0926-860X(95)00218-9.[Crossref]
  • 5. Krylov, O.V., Mamedov, A. & Mirzabekova, S. (1995). The regularities in the interaction of alkanes with CO2 on oxide catalysts. Catal. Today 24(3), 371-375.[Crossref]
  • 6. Ogonowski, J. & Skrzyńska, E. (2007) Mechanizm odwodornienia węglowodorów w obecności CO2. Biuletyn InstytutuTechnologii Nafty, 1(19), 27-33.
  • 7. Michorczyk, P. & Ogonowski, J. (2001) Analiza termodynamiczna reakcji konwersji propanu do propylenu w obecności ditlenku węgla, Czasopismo Techniczne, 4-Ch, 44-48.
  • 8. Michorczyk, P., Ogonowski, J., Kuśtrowski, P. & Chmielarz, L. (2008). Chromium oxide supported on MCM-41 as a highly active and selective catalyst for dehydrogenation of propane with CO2. Appl. Catal. A: General 349(1-2), 62-69. DOI: 10.1016/j.apcata.2008.07.008.[Crossref]
  • 9. Michorczyk, P., Ogonowski, J. & Niemczyk, M. (2010). Investigation of catalytic activity of CrSBA-1 materials obtained by direct method in the dehydrogenation of propane with CO2, Appl. Catal. A: General, 374(1-2), 142-149. DOI: 10.1016/j. apcata.2009.11.040.[Crossref]
  • 10. Morterra, C. & Magnacca, G. (1996). A case study: surface chemistry and surface structure of catalytic aluminas, as studied by vibrational spectroscopy of adsorbed species, Catal. Today 27(2-3), 497-532.[Crossref]
  • 11. Lavalley, J. (1996). Infrared spectrometric studies of the surface basicity of metal oxides and zeolites using adsorbed probe molecules. Catal. Today 27(3-4), 377-401.[Crossref]
  • 12. Busca, G., Finocchio, E., Ramis, G., Ricchiardi, G. (1996). On the role of acidity in catalytic oxidation, Catal.Today 32(1-4), 133-143.[Crossref]
  • 13. Xu, B., Zheng, B., Hua, W., Yue, Y. & Gao, Z. (2006). Support effect in dehydrogenation of propane in the presence of CO2 over supported gallium oxide catalysts, J. Catal. 239(2), 470-477. DOI:10.1016/j.jcat.2006.02.017.[Crossref]
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_v10026-012-0106-1
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