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2011 | 13 | 2 | 70-73
Tytuł artykułu

Novel catalytic method synthesis of calix[4]pyrroles using Preyssler and Wells-Dawson heteropolyacids

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
A catalytic synthesis of calix[4]pyrroles and N-confused calix[4]pyrroles by reaction of dialkyl or cycloalkyl ketones with pyrrole was performed using Preyssler, sodium30-tungsto pentaphosphate, [NaP5W30O110]14- and Wells-Dawson heteropolyacids as acidic catalysts. The process occurred under mild, eco-friendly and environmental friendly conditions and as a reusable, green catalyst at room temperature for 6 hours. The results showed that the yield for this synthesis is excellent with the use of Preyssler and Wells-Dawson type tungstophosphoric heteropolyacid, H6[P2W18O62], catalysts. The synthesis reaction of calix[4]pyrroles and N-confused calix[4]pyrroles was developed using different solvents and the best yields were obtained in chloroform.
Wydawca
Rocznik
Tom
13
Numer
2
Strony
70-73
Opis fizyczny
Daty
wydano
2011-01-01
online
2011-06-16
Twórcy
autor
  • Department of Chemistry, Islamic Azad University, Mashhad, IRAN
autor
  • Cluster for Molecular Chemistry, Department of Organic Chemistry, Radboud University Nijmegen, The Netherlands
Bibliografia
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  • Anzenbacher, Jr. P., Jursíková, K., Lynch, V.M., Gale, P.A. & Sessler, J.L. (1999). Calix[4]pyrroles containing deep cavities and fixed walls. Synthesis, structural studies, and anion binding properties of the isomeric products derived from the condensation of p-hydroxyacetophenone and Pyrrole. J. Am. Chem. Soc. 121, 11020-11021. DOI: 10.1021/ja993195n.[Crossref]
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  • Bamoharram, F.F., Heravi, M.M., Roshani, M., Jahangir, M. & Gharib, A. (2006). Preyssler catalyst, [NaP5W30O110]14-: A green, efficient and reusable catalyst for esterification of salicylic acid with aliphatic and benzylic alcohols. Applied Catalysis A: General. 302, 42-47. DOI: 10.1016/j.apcata.2005.12.021.[Crossref]
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_v10026-011-0027-4
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