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2007 | 9 | 3 | 33-37
Tytuł artykułu

Optimization of an active phase composition in the low-temperature nitric oxide reduction catalyst

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In the first research studies series a selection of the quantitative composition of catalyst active phase composition (iron, copper and manganese) deposited on mineral-carbon support was carried out. It was found on the basis of the selection studies series that the best results were attained when copper and manganese were used as catalyst components. The quantitative composition of the denitrogention catalyst was estimated using a statistical method of experiment planning and metals content changed in the range 0.5 - 1.5wt % for both metals. Catalyst activity in nitric oxide reduction by ammonia was determined in the dependence on an active phase composition in the temperature range 100 - 200°C, at GHSV (Gas Hour Space Velocity) 6 000 and 10 000 Nm3/m3h, NO concentration 400 ppm, NH3/NO ratio 1:1. A graphic presentation of the obtained results was made using the UNIPLOT program. The highest activity in nitric oxide reduction by ammonia presented copper - manganese catalysts prepared by the impregnation of mineral-carbon support with active metals salts solutions and calcination after each metal impregnation with copper (up to 1.5 wt %) and manganese (up to 1.5 wt %).
Słowa kluczowe
Wydawca

Rocznik
Tom
9
Numer
3
Strony
33-37
Opis fizyczny
Daty
wydano
2007-01-01
online
2007-11-06
Twórcy
  • Faculty of Chemistry, Department of Fuels Chemistry and Technology, Wrocław University of Technology, ul. Gdańska 7/9, 50-344 Wrocław, Poland
  • Faculty of Chemistry, Department of Fuels Chemistry and Technology, Wrocław University of Technology, ul. Gdańska 7/9, 50-344 Wrocław, Poland
  • Faculty of Chemistry, Department of Fuels Chemistry and Technology, Wrocław University of Technology, ul. Gdańska 7/9, 50-344 Wrocław, Poland
Bibliografia
  • Fumito N., Ikubisa H.: The state of the art of NOx control, Catal. Today, 1996, 29, 109.
  • Olivares J., Kułażyński M., Salwador L., Walendziewski J., Trawczyński J.: Laboratory and pilot plant performance of novel carbon monolithic catalysts development for selective flue gas d-NOxing at low temperature. Proc. Conf. Catalysis and Adsorption in Fuel Processing and Environmental Protection, Oficyna Wydawnicza Politechniki Wrocławskiej, Wrocław, 2002, 169.
  • Van der Grift C. J. G., Woldbuis A. F, Maaskant O. L.: The Shell DENOX-system for low temperature NOx removal, Catal. Today, 1996, 27, 23.
  • Wojciechowska M., Łomnicki S., Derewiński M., Haber J., Kryściak J.: Catalytic reduction of NO by carbon monoxide over supported copper oxide, Polish J. Environ. Studies, 1997, 6, 75.
  • Castillo S., Moran-Pineda M., MolinaV., Gomez R., Lopez T.: Catalytic reduction of nitric oxide on Pt and Rh catalysts supported on alumina and titania synthesized by the sol-gel method, Appl. Catal. B, 1998, 15, 203.[Crossref]
  • Bosch H., Janssen F.: Catalytic reduction of nitric oxides-a review on the fundamentals and technology, Catal. Today, 1997, 2, 370.
  • Kułażyński M., Walendziewski J., Bratek K.: Synthesis of mineral-carbon monolithic catalyst supports, Conference on Porous Ceramic Materials. PCM2005. Brugge, Flemish Institute for Technological Research (Vito), Belgium, 20 - 21 October 2005.
  • Kułażyński M., Walendziewski J.: DENOX activity of mineral carbon catalysts supported on monolithic material, Pol. J. Environ. Stud., 2006, 15, 6A, 95.
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_v10026-007-0049-0
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