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2012 | 1 | 9-11
Tytuł artykułu

Selective Oxidation of Alcohols Catalyzed by a Hemicryptophane-Ruthenium Complex

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Hemicryptophane, a covalent molecular capsule that is composed of a cyclotriveratrylene (CTV) host unit, a tris(2-aminoethyl)amine (tren) ligand, and three rigid phenyl spacers, is a useful ligand for preparing synthetic transition metal complexes containing well-defined cavities that mimic the active sites of metalloenzymes. A method for the selective oxidation of primary alcohols using 5 mol % hemicryptophane-ruthenium(II) dichloride as the catalyst and cerium(IV) ammonium nitrate (CAN) as the terminal oxidant is described. The corresponding aldehydes of both benzylic and aliphatic alcohols are afforded in good to excellent yields under mild conditions without significant over-oxidation to produce the corresponding carboxylic acids.
Wydawca
Rocznik
Tom
1
Strony
9-11
Opis fizyczny
Daty
otrzymano
2012-06-30
zaakceptowano
2012-07-25
online
2012-08-21
Twórcy
  • Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan
  • Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan
  • Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan
  • Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan
  • Department of Chemistry, Osaka Dental University, 8-1 Kuzuhahanazono-cho, Hirakata, Osaka 573-1121, Japan
autor
  • Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_supcat-2012-0002
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