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2010 | 8 | 1 | 7-16
Tytuł artykułu

Stationary inverted Lyman populations and free-free and bound-free emission of lower-energy state hydride ion formed by an exothermic catalytic reaction of atomic hydrogen and certain group I catalysts

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Rb+ to Rb2+ and 2K+ to K + K2+ each provide a reaction with a net enthalpy equal to the potential energy of atomic hydrogen. The presence of these gaseous ions with thermally dissociated hydrogen formed a plasma having strong VUV emission with a stationary inverted Lyman population. Significant Balmer α line broadening of 18 and 9 eV was observed from a rt-plasma of hydrogen with KNO3, and RbNO3, respectively, compared to 3 eV from a hydrogen microwave plasma. The reaction was exothermic since excess power of about 20 mW/cc was measured by Calvet calorimetry. We propose an energetic catalytic reaction involving a resonance energy transfer between hydrogen atoms and Rb+ or 2K+ to form a very stable novel hydride ion. Its predicted binding energy of 3.0471 eV with the fine structure was observed at 4071 Å, and its predicted bound-free hyperfine structure lines matched those observed for about 40 lines to within.01 percent. Characteristic emission from each catalyst was observed. This catalytic reaction may pump a CW HI laser.
Wydawca

Czasopismo
Rocznik
Tom
8
Numer
1
Strony
7-16
Opis fizyczny
Daty
wydano
2010-02-01
online
2009-11-15
Twórcy
autor
  • BlackLight Power, Inc., 493 Old Trenton Road, Cranbury, NJ, 08512, USA
  • BlackLight Power, Inc., 493 Old Trenton Road, Cranbury, NJ, 08512, USA
autor
  • BlackLight Power, Inc., 493 Old Trenton Road, Cranbury, NJ, 08512, USA
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11534-009-0052-6
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