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Luminescent properties of Li2 (Ca0.99, Eu0.01) SiO4: B3+ particles as a potential bluish green phosphor for ultraviolet light-emitting diodes

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In our study, the 1% mol Eu2+ doped Li2CaSiO4: B3+ phosphors were prepared by the combustion method as fluorescent material for ultraviolet, light-emitting diodes (UV-LEDs) used as a light source. The properties of Li2 (Ca0.99, Eu0.01) SiO4: B3+ phosphors with urea concentration, doping boric acid and a series of initiating combustion temperature were investigated. The crystallization and particle sizes of Li2 (Ca0.99, Eu0.01) SiO4: B3+ has been investigated by using powder X-ray diffraction (XRD) and transmission electron microscopy (TEM). Luminescence measurements showed that the phosphors can be efficiently excited by UV to the visible region, and exhibited bluish green light with a peak of 480 nm. The results showed that the boric acid was effective in improving the luminescence intensity of Li2 (Ca0.99, Eu0.01) SiO4: B3+ and the optimum molar ratio of boric acid to calcium nitrate was about 0.06. The optimized phosphors Li2 (Ca0.99, Eu0.01) SiO4: B0.063+ showed 180% improved emission intensity compared with that of the Li2 (Ca0.99, Eu0.01) SiO4 phosphors under ultraviolet (λex =287 nm) excitation.

Opis fizyczny
  • Key Laboratory of Catalysis and Material Science of the State Ethnic Affairs Commission & Ministry of Education, Hubei Province, College of Chemistry and Material Science, South Central University for Nationalities, Wuhan, 430074, PR China
  • Key Laboratory of Catalysis and Material Science of the State Ethnic Affairs Commission & Ministry of Education, Hubei Province, College of Chemistry and Material Science, South Central University for Nationalities, Wuhan, 430074, PR China,
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