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2014 | 12 | 12 | 1248-1254
Tytuł artykułu

Catalytic production of oxygenated additives by glycerol etherification

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In this work the etherification reaction of glycerol with isobutene (IB) and tert-butyl alcohol (TBA) has been studied with the aim of preparing mixtures with high content of poly-substituted ethers. The results obtained using solid acid catalysts have shown that the reaction with IB proceeds at a high rate but the formation of undesired di-isobutene (DIB) represents a serious problem when catalysts with high density of acid sites, such as Amberlyst, are used. When using TBA as a reactant, the main problem is the formation of water that, due to thermodynamic reasons, prevents the formation of poly-substituted ethers regardless of the catalyst used. Some preliminary experiments carried out with a water permselective tubular membrane have demonstrated that the yield of poly-substituted ethers significantly increases once water was selectively removed from the reaction medium by recirculation of the gas phase.
Wydawca

Czasopismo
Rocznik
Tom
12
Numer
12
Strony
1248-1254
Opis fizyczny
Daty
wydano
2014-12-01
online
2014-06-07
Twórcy
  • “Nicola Giordano”
  • “Nicola Giordano”
  • University of Messina
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-014-0546-y
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