Supramolecular complexes of podand ligands with xenon

• Autorzy: Błażej Gierczyk , Radosław Pankiewicz
• Języki publikacji: EN

Abstrakty

EN

Formation of stable complexes between xenon and podand polyoxyethylene ligands was ascertained. The complexation process was studied by 129Xe NMR titration, NMR diffusiometry and heteronuclear NOE measurements. The ligands studied form a 1:1 complexes with Xe(0). Their stability constants depend on the ligand structure, i.e., polyoxyethylene chain length, number of complexating polyether units and the topology of the anchoring centre.

Słowa kluczowe

EN

Podand; Xenon; 129Xe NMR; Complexation; Supramolecular Chemistry

• Czasopismo: Open Chemistry
• Rocznik: 2014
• Tom: 12
• Numer: 5
• Strony: 624-634

Daty

wydano

2014-05-01

online

2014-02-21

Twórcy

autor

Błażej Gierczyk

• Adam Mickiewicz University in Poznań,

autor

Radosław Pankiewicz

• Adam Mickiewicz University in Poznań

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Identyfikatory

DOI

10.2478/s11532-014-0525-3