Czasopismo
Tytuł artykułu
Autorzy
Warianty tytułu
Języki publikacji
Abstrakty
The aim of this study was to compare several anion exchangers and to investigate the capacity of Amberlite IRA410 to remove zinc as chloride [ZnCl3]− from hydrochloric solutions (1 M). Influence of the process parameters such as stirring rate, resin quantity and zinc initial concentration over the removal process, was considered. The highest experimental ionic exchange capacity between the considered anionic exchangers, in the same working conditions (500 rpm, 5 g resin and 500 mg L−1), was obtained for Amberlite IRA410, 8.34 mg g−1. With an increase of zinc ions concentration, ionic exchange capacity increased up to 19.31 mg g−1 (1100 mg L−1). The experimental data were analysed using Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models. The results were also analyzed using sorption kinetics models, pseudo-first-, pseudo-second-order, intra-particle and film diffusion models. From the Dubinin-Radushkevich and Temkin isotherm models the mean free energy and heat of sorption were calculated to be 7.45 kJ mol−1, respectively 1×10−4 kJ mol−1, which indicates that zinc sorption is characterized by a physisorption process. Kinetic studies showed that the adsorption followed a pseudo-second-order kinetic model.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Numer
Strony
821-828
Opis fizyczny
Daty
wydano
2014-08-01
online
2014-05-01
Twórcy
autor
- Babeş-Bolyai University
autor
- Babeş-Bolyai University, andrada@chem.ubbcluj.ro
autor
- Babeş-Bolyai University
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-014-0504-8