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2014 | 12 | 3 | 283-306
Tytuł artykułu

Crystallographic and structural characterization of heterometallic platinum complexes Part V. Heteropentanuclear complexes

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
This review classifies and analyzes over eighty heteropentanuclear Pt complexes. There are eight types of metal combinations: Pt4M, Pt3M2, Pt2M3, PtM4, Pt3MM′, Pt2M2M′, PtM2M′2 and PtM3M′. The five metal atoms are in a wide variety of arrangements: trigonal-bipyramidal (most common), square-pyramidal, spike-triangular, butterfly, cubane, linear and one unique. Platinum bonds to a variety of triad partner metal atoms, soft, through borderline to hard. The shortest Pt-M bond distances for non-transition and transition M are 2.406(4) Å (M = Ge) and 2.30(1) Å (M = Co). The shortest Pt-Pt bond distance is 2.580(1) Å. Several relationships between the structural parameters were found and are discussed. Several complexes exist in two isomeric forms and others contain two crystallographically independent molecules. Both the isomers as well as independent molecules are examples of distortion isomerism.
Słowa kluczowe
Wydawca

Czasopismo
Rocznik
Tom
12
Numer
3
Strony
283-306
Opis fizyczny
Daty
wydano
2014-03-01
online
2013-12-21
Twórcy
autor
  • Comenius University in Bratislava
  • York University
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-013-0382-5
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