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Czasopismo
2014 | 12 | 2 | 220-226
Tytuł artykułu

The synthesis, structure and physical properties of lanthanide(III) complexes with nicotinic acid

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
This article reports the synthesis of novel, rare-earth coordination complexes with nicotinic acid. Three compounds with the general formula Ln2[(C5H4NCOO)6(H2O)4] (Ln = Yb, 1; Ln = Gd, 2; Ln = Nd, 3) were prepared from relatively cheap and readily available reactants. Their compositions and structure were characterized by IR spectroscopy and single-crystal X-ray diffraction. The magnetic and thermogravimetric properties were also studied. The complexes consist of centrosymetric, dimeric molecules having all six nicotinato ligands coordinated with the central atom in the bidentate mode. The coordination environment of the Ln3+ for all three compounds is 8. Here we describe the crystal structure of Yb and Gd complexes with nicotinic acid.
Wydawca

Czasopismo
Rocznik
Tom
12
Numer
2
Strony
220-226
Opis fizyczny
Daty
wydano
2014-02-01
online
2013-11-27
Twórcy
autor
  • University of Maribor
  • University of Ljubljana
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-013-0366-5
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