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2013 | 11 | 12 | 1959-1963
Tytuł artykułu

Complexation of nickel (II) ion with B3 vitamin in aqueous dimethyl sulfoxide

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The stability change of nickel(II) ion complexes including one and two nicotinamide (B3 vitamin) molecules in aqueous dimethyl sulfoxide (XDMSO = 0–0.85 m.f.) was studied at 298.2±0.1 K and 0.25 ionic strength value (NaClO4) using the potentiometric method. The first stage constant of complexation increased until organic solvent concentration was 0.5 m.f. and reduced at higher DMSO content. The difference between complex and central ions solvation is a dominating contribution into the Gibbs energy change of mononicotinamide complex formation reaction. When the second ligand molecule was bonded into the coordination compound, the nicotinamide contribution to ΔtrGr rose and became prevailing at XDMSO = 0.7–0.85. The ligand was found to replace a water molecule in the coordination sphere of the cation according to spectrophotometric study results. [...]
Wydawca

Czasopismo
Rocznik
Tom
11
Numer
12
Strony
1959-1963
Opis fizyczny
Daty
wydano
2013-12-01
online
2013-09-26
Twórcy
autor
  • Research Institute of Thermodynamics and Kinetics of Chemical Processes, Ivanovo State University of Chemistry and Technology, Ivanovo, 153000, Russia, kax504@isuct.ru
  • Research Institute of Thermodynamics and Kinetics of Chemical Processes, Ivanovo State University of Chemistry and Technology, Ivanovo, 153000, Russia
  • Research Institute of Thermodynamics and Kinetics of Chemical Processes, Ivanovo State University of Chemistry and Technology, Ivanovo, 153000, Russia
  • Research Institute of Thermodynamics and Kinetics of Chemical Processes, Ivanovo State University of Chemistry and Technology, Ivanovo, 153000, Russia
Bibliografia
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  • [3] J.P. Thyssen, A. Linneberg, T. Menné, J.D. Johansen, Contact Dermatitis 57, 287 (2007) http://dx.doi.org/10.1111/j.1600-0536.2007.01220.x[Crossref]
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  • [12] K.V. Grazhdan, N.N. Kuranova, S.V. Dushina, V.A. Sharnin, Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhn. 51, 30 (2008) (in Russian)
  • [13] K.V. Grazhdan, G.A. Gamov, S.V. Dushina, V.A. Sharnin, Russ. J. Coord. Chem. 35, 912 (2009) http://dx.doi.org/10.1134/S1070328409120094[Crossref]
  • [14] V.A. Borodin, V.P. Vasil’ev, E.V. Kozlovskii, Zhurn. Neorg. Khim. 31, 10 (1986) (in Russian)
  • [15] V.P. Vasil’ev, V.A. Borodin, E.V. Kozlovskii, Computers’ application for calculations in analytical chemistry (Vysshaya shkola, Moscow, 1993) (in Russian)
  • [16] V.O. Reikhsfel’d, V.L. Ruban, I.E. Saratov, V.V. Korol’ko, Laboratory works on the technology of basic organic synthesis (Khimia, Moscow, 1966) (in Russian)
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-013-0325-1
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