Crystallographic and structural characterization of heterometallic platinum compounds part IV: heterotetranuclear clusters

• Autorzy: Milan Melník , Peter Mikuš , Clive Holloway
• Języki publikacji: EN

Abstrakty

EN

This review includes over two hundred heterotetranuclear platinum clusters. The clusters are of the compositions Pt3M, Pt3M2, PtM3, Pt′2MM′, PtM2M′ and PtMM′M”. There are twenty five different M atoms (transition and non-transition) as a partner(s) of platinum. The four metal atoms are found in a tetrahedral, planar-rhombohedral, butterfly, spited-triangular, cubane, eight - and oligo-membered rings and a unique structures. There is wide variety of the ligands from uni to- undecadentate, with the most common P and C donor sites. The shortest Pt-M (transition) versus Pt-M (non-transition) bond distances are 2.4833(8)Å (M=Pd) vs. 2.4365(5)Å (Ge). Several relationships between the various structural parameters were found and are discussed. [...]

Słowa kluczowe

EN

Review; Heterotetranuclear; Platinum; Crystallography; Classification

• Czasopismo: Open Chemistry
• Rocznik: 2013
• Tom: 11
• Numer: 12
• Strony: 1902-1953

Daty

wydano

2013-12-01

online

2013-09-26

Twórcy

autor

Milan Melník

• Department of Pharmaceutical Analysis and Nuclear Pharmacy, Faculty of Pharmacy, Comenius University in Bratislava, SK-832 32, Bratislava, Slovak Republic,

autor

Peter Mikuš

• Department of Pharmaceutical Analysis and Nuclear Pharmacy, Faculty of Pharmacy, Comenius University in Bratislava, SK-832 32, Bratislava, Slovak Republic

autor

Clive Holloway

• Department of Chemistry, York University, North York, M3J 1P3, Ontario, Canada

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Identyfikatory

DOI

10.2478/s11532-013-0320-6