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2013 | 11 | 11 | 1786-1798
Tytuł artykułu

Chemical modification and characterization of poly(ethylene terephthalate) surfaces for collagen immobilization

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The functionalization of poly(ethylene terephthalate) (PET) surface films by reactions with multifunctional amines such as triethylenetetramine (TETA), and tetraethylenepentamine (TEPA) was investigated. For the functionalization of PET films surface we used a new way of treatment, a “sandwich model”. Physical-chemical properties of functionalized PET films were analysed. Qualitative and quantitative determination of the introduced amine groups were examined by means of Fourier Transform Infrared Attenuated Total Reflexion (FTIR - ATR), X-ray photoelectron spectroscopy (XPS), and potentiometric titration. Gained wetting properties were determined by using contact angle measurements and thoroughly analysed by acid-base approach. In addition, surface topography was investigated by atomic force microscopy (AFM). The amount of the introduced amino groups after TETA incorporation has been found to be two times higher as compared to TEPA. Wetting properties were significantly improved after aminolysis. Surface free energy was higher for PET - TETA treated film than that observed for PET - TEPA treated which is in accordance with titration results. The collagen immobilization onto PET treated films was evidenced by using AFM and subsequently by using XPS. [...]
Słowa kluczowe
Wydawca

Czasopismo
Rocznik
Tom
11
Numer
11
Strony
1786-1798
Opis fizyczny
Daty
wydano
2013-11-01
online
2013-08-25
Twórcy
  • “Petru Poni” Institute of Macromolecular Chemistry, 700487, Iasi, Romania, miamiara@icmpp.ro
  • Laboratory for Characterization and Processing of Polymers, Faculty of Mechanical Engineering, Institute for Engineering Materials and Design, University of Maribor, SI-2000, Maribor, Slovenia
  • Laboratory for Characterization and Processing of Polymers, Faculty of Mechanical Engineering, Institute for Engineering Materials and Design, University of Maribor, SI-2000, Maribor, Slovenia
autor
autor
  • Laboratory for Characterization and Processing of Polymers, Faculty of Mechanical Engineering, Institute for Engineering Materials and Design, University of Maribor, SI-2000, Maribor, Slovenia
  • Institute of Chemistry, Rheology & Colloid Science, Karl Franzens University, 8010, Graz, Austria
  • “Petru Poni” Institute of Macromolecular Chemistry, 700487, Iasi, Romania
  • “Petru Poni” Institute of Macromolecular Chemistry, 700487, Iasi, Romania
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-013-0319-z
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