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Czasopismo
2013 | 11 | 10 | 1634-1643
Tytuł artykułu

Use of direct immersion solid-phase microextraction on polyacrylate and polydimethylsiloxane stationary phases for simultaneous determination of the neutral and basic pharmaceuticals in wastewater

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Direct immersion solid-phase microextraction has been optimized and applied to the simultaneous determination of the neutral and basic pharmaceuticals: caffeine, carbamazepine, clomipramine, chlorprothixene and clotrimazole at low concentrations in municipal wastewater. Two absorption type stationary phases: polydimethylsiloxane (PDMS) and polyacrylate (PA) have been found to be most effective for extraction of target analytes. The separation and detection were carried out by gas chromatograph coupled with mass spectrometer working in the selected ion monitoring mode. The method was validated for linearity, detection and quantitation limits, selectivity and precision. The average correlation coefficient of the calibration curves was 0.9933. The LOD values in influent and effluent wastewater were in the range of 10–145 ng L−1 and 4–111 ng L−1, respectively, which were a bit higher than those in the deionized water due to matrix effect. The high values of distribution coefficient (K fs ) in PDMS/water and PA/water systems (log K fs between 3.05 and 4.23) indicates the very high applicability of these stationary phases for determination of carbamazepine, clomipramine, chlorprothixene and clotrimazole in water samples. [...]
Wydawca

Czasopismo
Rocznik
Tom
11
Numer
10
Strony
1634-1643
Opis fizyczny
Daty
wydano
2013-10-01
online
2013-07-19
Twórcy
  • Institute of Chemistry, University of Białystok, 15-399, Białystok, Poland, ukrajew@uwb.edu.pl
  • Institute of Chemistry, University of Białystok, 15-399, Białystok, Poland
Bibliografia
  • [1] M.S. Diaz-Cruz, D. Barcelo, in: D. Barcelo (Ed.), Emerging organic pollutants in wastewaters and sludge (Springer-Verlag, Berlin Heidelberg, 2004) Vol. 5, 227
  • [2] D.W. Kolpin, E.T. Furlong, M.T. Meyer, E.M. Thurman, S.D. Zaugg, L.B. Barber, H.T. Buxton, Environ. Sci. Technol. 36, 1202 (2002) http://dx.doi.org/10.1021/es011055j[Crossref]
  • [3] K.K. Barnes, D.W. Kolpin, E.T. Furlong, S.D. Zaugg, M.T. Meyer, L.B. Barber, Sci. Total Environ. 402, 192 (2008) http://dx.doi.org/10.1016/j.scitotenv.2008.04.028[Crossref]
  • [4] L. Lindqvist, T. Tuhkanen, L. Kronberg, Water Res. 39, 2219 (2005) http://dx.doi.org/10.1016/j.watres.2005.04.003[Crossref]
  • [5] M. Carballa, F. Omil, J.M. Lema, M. Llompart, C. Garcia-Jares, I. Rodriguez, M. Gomez, T. Ternes, Water Res. 38, 2918 (2004) http://dx.doi.org/10.1016/j.watres.2004.03.029[Crossref]
  • [6] O.A.H. Jones, N. Voulvoulis, J.N. Lester, Water Res. 36, 5013 (2002) http://dx.doi.org/10.1016/S0043-1354(02)00227-0[Crossref]
  • [7] C.G. Daughton, T. Ternes, Environ. Health Perspect. 107, 907 (1999) http://dx.doi.org/10.1289/ehp.99107s6907[Crossref]
  • [8] K. Kümmerer, Pharmaceuticals in the environment: sources, fate, effects and risks, 3rd edition (Springer-Verlag, Berlin, Heidelberg, New York, 2008) http://dx.doi.org/10.1007/978-3-540-74664-5[Crossref]
  • [9] J.C. Chee-Sanford, R.I. Mackie, S. Koike, I. Krapac, S. Maxwell, Y. Lin, R.I. Aminov, J. Environ. Qual. 38, 1086 (2009) http://dx.doi.org/10.2134/jeq2008.0128[Crossref]
  • [10] S.P. Singh, A. Azua, A. Chaudhary, S. Khan, K.L. Willett, P.R. Gardinali, Ecotoxicology 19, 338 (2010) http://dx.doi.org/10.1007/s10646-009-0416-0[Crossref]
  • [11] D.R. Baker, B. Kasprzyk-Hordern, J. Chromatogr. A 1218, 1620 (2011) http://dx.doi.org/10.1016/j.chroma.2011.01.060[Crossref]
  • [12] A. Karnjanapiboonwong, J.G. Suski, A.A. Shah, Q. Cai, A.N. Morse, T.A. Anderson, Water, Air, Soil Pollut. 216, 257 (2011) http://dx.doi.org/10.1007/s11270-010-0532-8[Crossref]
  • [13] J.L. Santos, I. Aparicio, E. Alonso, M. Callejón, Anal. Chim. Acta, 550, 116 (2005) http://dx.doi.org/10.1016/j.aca.2005.06.064[Crossref]
  • [14] R. Rosal, A. Rodriguez, J.A. Perdigon-Melon, A. Petre, E. Garcia-Calvo, M.J. Gomez, A. Aguera, A.R. Fernandez-Alba, Water Res. 44, 578 (2010) http://dx.doi.org/10.1016/j.watres.2009.07.004[Crossref]
  • [15] J. Martín, D. Camacho-Munoz, J.L. Santos, I. Aparicio, E. Alonso, J. Hazard. Mater. 239, 40 (2012) http://dx.doi.org/10.1016/j.jhazmat.2012.04.068[Crossref]
  • [16] J.L. Santos, I. Aparicio, E. Alonso, Environ. Int., 33, 596 (2007) http://dx.doi.org/10.1016/j.envint.2006.09.014[Crossref]
  • [17] R. Rosal, A. Rodríguez, J.A. Perdigón-Melón, A. Petre, E. García-Cavalo, M.J. Gómez, A. Agüera, A.R. Fernández-Alba, Water Res. 44, 578 (2010) http://dx.doi.org/10.1016/j.watres.2009.07.004[Crossref]
  • [18] M. Hijosa-Valsero, V. Matamoros, J. Martín-Villacorta, E. Bécares, J.M. Bayona, Water Res. 44, 1429 (2010) http://dx.doi.org/10.1016/j.watres.2009.10.032[Crossref]
  • [19] E. Zuccato, S. Castiglioni, R. Fanelli, J. Hazard. Mater. 122, 205 (2005) http://dx.doi.org/10.1016/j.jhazmat.2005.03.001[Crossref]
  • [20] Z.L. Zhang, J.L. Zhou, J. Chromatogr. A 1154, 205 (2007) http://dx.doi.org/10.1016/j.chroma.2007.03.105[Crossref]
  • [21] P.H. Roberts, K.V. Thomas, Sci. Total Environ. 356, 143 (2006) http://dx.doi.org/10.1016/j.scitotenv.2005.04.031[Crossref]
  • [22] C. Lacey, S. Basha, A. Morrissey, J. M. Tobin, Environ. Monit. Assess. 184, 1049 (2012) http://dx.doi.org/10.1007/s10661-011-2020-z[Crossref]
  • [23] Q. Huang, T. Yu, C. Tang, X. Peng, J. Chromatogr. B, 1217, 3481 (2010)
  • [24] J. Pawliszyn, S. Liu, Anal. Chem. 59, 1475 (1987) http://dx.doi.org/10.1021/ac00137a024[Crossref]
  • [25] J. Pawliszyn, Solid-phase microextraction, theory and practice (Wiley, New York, 1997)
  • [26] A. Joss, E. Keller, A.C. Alder, A. Göbel, C.S. McArdell, T.A. Ternes, Water Res.; 39, 3139 (2005) http://dx.doi.org/10.1016/j.watres.2005.05.031[Crossref]
  • [27] F. Hernandez, J. Beltran, F.J. Lopez, J.V. Gaspar, Anal. Chem. 72, 2313 (2000) http://dx.doi.org/10.1021/ac991115s[Crossref]
  • [28] R. Doong, S. Chang, Anal. Chem. 72, 3647 (2000) http://dx.doi.org/10.1021/ac000040l[Crossref]
  • [29] I. Valor, M. Perez, C. Cortada, D. Apraiz, J.C. Molto, G. Font, J. Sep. Sci. 34, 1 (2001)
  • [30] D.A. Lambropoulou, V.A. Sakkas, T.A. Albanis, Anal. Bioanal. Chem. 374, 932 (2002) http://dx.doi.org/10.1007/s00216-002-1549-7[Crossref]
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-013-0296-2
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