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2013 | 11 | 9 | 1518-1526
Tytuł artykułu

The Ti-Fe-P system: phase equilibria and crystal structure of phases

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Abstract Phase equilibria was investigated in the Ti-Fe-P system at T = 1070 K in the region 0–67 at.% of P, employing X-ray powder diffraction. The two ternary compounds, namely Ti0.5–0.8Fe1.5−1.2P (Co2Si-type; space group Pnma; a = 0.5964(2)–0.6011(3), b = 0.3575(3)–0.3600(1), c = 0.6828(2)–0.6882(2) nm) and Ti0.85−1.25Fe1.15−0.75P (ZrNiAl-type; space group P-62m; a = 0.6071(4)–0.6117(1), c = 0.3510(9)–0.3506(1) nm) exist in the Ti-Fe-P system at this temperature. The crystal structure of the Ti0.85–1.25Fe1.15−0.75P compound was additionally determined by X-ray single crystal diffraction on the phase with stoichiometric composition. The substitutions of Ti by Fe were observed for Ti5P3.16, Ti3P and TiP phases, and Fe for Ti in the case of Fe3P, Fe2P binary compounds. Graphical abstract [...]
Wydawca

Czasopismo
Rocznik
Tom
11
Numer
9
Strony
1518-1526
Opis fizyczny
Daty
wydano
2013-09-01
online
2013-06-29
Twórcy
autor
  • Laboratory MOLTECH — Anjou, UMR-CNRS 6200, University of Angers, 49045, Angers, France
  • Department of Analytical Chemistry, Ivan Franko National University of Lviv, UA-79005, Lviv, Ukraine, mashadzev@gmail.com
  • Department of Chemistry, University of Alberta, Edmonton, Alberta, T6G 2G2, Canada
  • Department of Analytical Chemistry, Ivan Franko National University of Lviv, UA-79005, Lviv, Ukraine
Bibliografia
  • [1] A.O. Oliynyk, Y.F. Lomnytska, M.V. Dzevenko, S.S. Stoyko, A. Mar, Inorg. Chem. 52, 983 (2013) http://dx.doi.org/10.1021/ic302243p[Crossref]
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-013-0282-8
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