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2013 | 11 | 8 | 1381-1392
Tytuł artykułu

Cobalt electrodeposition onto polycrystalline gold from ammoniacal solutions

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Języki publikacji
EN
Abstrakty
EN
In the present work, the cobalt electrodeposition onto polycrystalline gold electrodes from aqueous solutions containing 0.01M CoSO4 + 1 M (NH4)2SO4 at pH=7 was analyzed. Linear voltammetry results suggested a change in the kinetic of the cobalt electrodeposition. In all cases, the nucleation rate (A), the number of active nucleation sites (N 0) and the saturation number of nuclei (N s ) values were potential dependent. The calculated Gibbs free energy (ΔG) for this system was 1.88×10−20 J nuclei−1 and the transfer coefficient for the Hydrogen Electroreduction Reaction (HER) was 0.47. [...]
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Wydawca

Czasopismo
Rocznik
Tom
11
Numer
8
Strony
1381-1392
Opis fizyczny
Daty
wydano
2013-08-01
online
2013-06-01
Twórcy
  • Academic Area of Chemistry, Autonomous University of Hidalgo State, CP. 42186 Mineral de la Reforma, Hidalgo, Mexico, hhuizar@uaeh.edu.mx
  • Academic Academic Area of Earth Sciences and Materials, Autonomous University of Hidalgo State, CP. 42186 Mineral de la Reforma, Hidalgo, Mexico
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