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2013 | 11 | 8 | 1352-1359
Tytuł artykułu

The first transition metal iodato peroxido complex: the synthesis, vibrational spectra and crystal structure from powder diffraction data of K3[V2O2(O2)4(IO3)]·H2O

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The first transition metal iodato peroxido complex, K3[V2O2(O2)4(IO3)]·H2O (I), was prepared by crystallization from the KVO3 - KIO3 - H2O2 - H2O - ethanol (HNO3) solution. The dinuclear anion is immediately decomposed in aqueous solution; the 51V NMR spectrum exhibits signals corresponding to [VO(O2)2(H2O)]−, [V2O2(OH)(O2)4]3− and H2VO4− species only. The IR and Raman spectra contain all characteristic bands of the VO(O2)2 group and the coordinated IO3− ligand. Based on the positions of bands assigned to the vibrations of the VO(O2)2 groups a pentagonal pyramidal arrangement around the vanadium atoms can be supposed. The crystal structure was solved from X-ray synchrotron powder data by direct space method and refined by energy minimization in the solid state employing a hybrid PBE0 functional. This crystal and molecular structure, has confirmed the presence of hexacoordinated vanadium atoms and revealed asymmetric dinuclear structure of the [V2O2(O2)4(IO3)]3− ion. The coordination spheres of vanadium atoms are different - the IO3− anion is coordinated only to one vanadium center. A thermal analysis of the complex confirmed the presence of water molecules in the crystal structure and revealed a considerable stability of the dehydrated complex. [...]
Wydawca

Czasopismo
Rocznik
Tom
11
Numer
8
Strony
1352-1359
Opis fizyczny
Daty
wydano
2013-08-01
online
2013-06-01
Twórcy
  • Department of Inorganic Chemistry, Faculty of Natural Sciences, Comenius University in Bratislava, 842 15, Bratislava 4, Slovak Republic
  • Department of Inorganic Chemistry, Faculty of Natural Sciences, Comenius University in Bratislava, 842 15, Bratislava 4, Slovak Republic
  • Department of Inorganic Chemistry, Faculty of Natural Sciences, Comenius University in Bratislava, 842 15, Bratislava 4, Slovak Republic, chrappova@fns.uniba.sk
  • Institute of Inorganic Chemistry, Slovak Academy of Sciences, SK-845 36, Bratislava, Slovak Republic
  • Laboratory of Crystallography, DPMC-MaNEP, University of Geneva, CH-1211, Geneva, Switzerland
autor
  • Swiss-Norwegian Beam Lines at ESRF, BP-220, 38043, Grenoble, France
Bibliografia
  • [1] H. Mimoun, L. Saussine, E. Daire, M. Postel, J. Fischer, R Weiss, J. Am. Chem. Soc. 105, 3101 (1983) http://dx.doi.org/10.1021/ja00348a025[Crossref]
  • [2] V. Conte, B. Floris, Dalton Trans. 40, 1419 (2011) http://dx.doi.org/10.1039/c0dt00706d[Crossref]
  • [3] A.S. Tracey, G.R. Wilsky, E.S. Takeuchi, Vanadium. Chemistry, Biochemistry, Pharmacology and Practical Applications (CRC Press, Taylor & Francis Group, Boca Raton, 2007) 183
  • [4] D. Rehder, Bioinorganic Vanadium Chemistry (John Willey & Sons, Chichester 2008) 105 http://dx.doi.org/10.1002/9780470994429[Crossref]
  • [5] D.C. Crans, J.J. Smee, E. Gaidamaustas, Y. Yang, Chem. Rev. 104, 849 (2004) http://dx.doi.org/10.1021/cr020607t[Crossref]
  • [6] P. Schwendt, P. Petrovič, D. Úškert, Z. Anorg. All. Chem. 466, 232 (1980) http://dx.doi.org/10.1002/zaac.19804660129[Crossref]
  • [7] R. Stomberg, Acta Chem. Scand. A 39, 125 (1985)
  • [8] P. Schwendt, J. Tyršelová, F. Pavelčík, Inorg. Chem. 34, 1964 (1995) http://dx.doi.org/10.1021/ic00111a053[Crossref]
  • [9] P. Schwendt, A. Oravcová, J. Tyršelová, F. Pavelčík, Polyhedron 15, 4507 (1996) http://dx.doi.org/10.1016/0277-5387(96)00185-4[Crossref]
  • [10] C.F. Sun, C.L. Hu, X. Xu, B.P. Yang, J.G. Mao, J. Am. Chem. Soc. 133, 5561 (2011) http://dx.doi.org/10.1021/ja200257a[Crossref]
  • [11] B.P. Yang, C.L. Hu, C.F. Sun, J.H. Zhang, J.G. Mao, Chem. Mater. 22, 1545 (2010) http://dx.doi.org/10.1021/cm902902j[Crossref]
  • [12] W.C. Bray, H.A. Liebhafsky, J. Am. Chem. Soc. 53, 38 (1931) http://dx.doi.org/10.1021/ja01352a006[Crossref]
  • [13] ?. Treindl, R.M. Noyes, J. Phys. Chem. 97, 11354 (1993) http://dx.doi.org/10.1021/j100145a039[Crossref]
  • [14] P. Antal, J. Tatiersky, P. Schwendt, Z. Žák, R. Gyepes, J. Mol. Struct. 1032, 240 (2013) http://dx.doi.org/10.1016/j.molstruc.2012.10.019[Crossref]
  • [15] J.W. Visser, J. Appl. Crystallogr. 2, 89 (1969) http://dx.doi.org/10.1107/S0021889869006649[Crossref]
  • [16] A.Le Bail, H. Duroy, J.L. Fourquet, Mater. Res. Bull. 23, 447 (1988) http://dx.doi.org/10.1016/0025-5408(88)90019-0[Crossref]
  • [17] J. Rodriguez-Carvajal, Physica B 192, 55 (1993) http://dx.doi.org/10.1016/0921-4526(93)90108-I[Crossref]
  • [18] V. Favre-Nicolin, R. Černý, J. Appl. Crystallogr. 35, 734 (2002) http://dx.doi.org/10.1107/S0021889802015236[Crossref]
  • [19] V. Favre-Nicolin, R. Černý, Z. Kristallogr. 219, 847 (2004) http://dx.doi.org/10.1524/zkri.219.12.847.55869[Crossref]
  • [20] G. Kresse, J. Hafner, Phys. Rev. B48, 13115 (1993) [Crossref]
  • [21] G. Kresse, J. Furthmüller, Phys. Rev. B54, 11169 (1996) [Crossref]
  • [22] G. Kresse, J. Furthmüller, Comp. Mater. Sci. 6, 15 (1996) http://dx.doi.org/10.1016/0927-0256(96)00008-0[Crossref]
  • [23] J.P. Perdew, M. Ernzerhof, K. Burke, J. Chem. Phys. 105, 9982 (1996) http://dx.doi.org/10.1063/1.472933[Crossref]
  • [24] P.E. Blöchl, Phys. Rev. B50, 17953 (1994) [Crossref]
  • [25] G. Kresse, J. Joubert, Phys. Rev. B59, 1758 (1999) [Crossref]
  • [26] G. Kresse, J. Hafner, J. Phys. Condens. Mat. 6, 8245 (1994) http://dx.doi.org/10.1088/0953-8984/6/40/015[Crossref]
  • [27] Xue-An Chen, Li Zhang, Xin-An Chang, He-Gui Zang, Wei-Qiang Xiao, Acta Crystallogr. C62, i76 (2006)
  • [28] A. Le Bail, Ľ. Smrčok, Powder Diffr. 26, 321 (2011) http://dx.doi.org/10.1154/1.3660160[Crossref]
  • [29] M. Oszajca, Ľ. Smrčok, H. Pálková, W. Łasocha, J. Mol. Struct. 1021, 70 (2012) http://dx.doi.org/10.1016/j.molstruc.2012.04.060[Crossref]
  • [30] Ľ. Smrčok, V. Jorík, E. Scholtzová and V. Milata, Acta Crystallogr. B63, 477 (2007) [Crossref]
  • [31] Ľ. Smrčok, M. Brunelli, M. Boča and M. Kucharík, J. Appl. Crystallogr. 41, 634 (2008) http://dx.doi.org/10.1107/S0021889808005876[Crossref]
  • [32] Ľ. Smrčok, B. Bitschnau, Y. Filinchuk, Cryst. Res. Technol. 44 978 (2009) http://dx.doi.org/10.1002/crat.200900339[Crossref]
  • [33] Ľ. Smrčok, R. Černý, M. Boča, I. Macková, B. Kubíková, Acta Crystallogr. C 66, I16 (2010) http://dx.doi.org/10.1107/S0108270109055140[Crossref]
  • [34] A.L. Spek, Acta Crystallogr. D65, 148 (2009)
  • [35] M. I. Aroyo, A. Kirov, C. Capillas, J. M. Perez-Mato, H. Wondratschek, Acta Crystallogr. A62, 115 (2006) [Crossref]
  • [36] M. I. Aroyo, J. M. Perez-Mato, C. Capillas, E. Kroumova, S. Ivantchev, G. Madariaga, A. Kirov, H. Wondratschek, Z. Kristallogr. 221, 15 (2006) http://dx.doi.org/10.1524/zkri.2006.221.1.15[Crossref]
  • [37] M. I. Aroyo, J. M. Perez-Mato, D. Orobengoa, E. Tasci, G. de la Flor, A. Kirov, Bulg. Chem. Commun. 43 183 (2011)
  • [38] D. Rehder, Bioinorganic Vanadium Chemistry (John Willey & Sons, Chichester 2008) 18 http://dx.doi.org/10.1002/9780470994429[Crossref]
  • [39] A.S. Tracey, G.R. Wilsky, E.S. Takeuchi, Vanadium. Chemistry, Biochemistry, Pharmacology and Practical Applications (CRC Press, Taylor & Francis Group, Boca Raton, 2007) 83
  • [40] P. Schwendt, M. Sýkora, Collect. Czech. Chem. Commun. 55, 1485 (1990) http://dx.doi.org/10.1135/cccc19901485[Crossref]
  • [41] J. Chrappová, P. Schwendt, M. Sivák, M. Repiský, V.G. Malkin, J. Marek, Dalton Trans. 465 (2009)
  • [42] V.L. Pavlov, A.V. Melezhik, Zh. Neorg. Khim. 20, 678 (1975)
  • [43] P. Schwendt, M. Pisárčik, Chem. Papers 42, 305 (1988)
  • [44] P. Schwendt, K. Volka, M. Suchánek, Spectrochim. Acta 44 A, 839 (1988)
  • [45] J. Chrappová, P. Schwendt, J. Marek, J. Fluorine Chem. 126, 1297 (2005) http://dx.doi.org/10.1016/j.jfluchem.2005.06.009[Crossref]
  • [46] B.W. Lucas, Acta Cryst. C40, 1989 (1984)
  • [47] A.E. Lapshin, Y.I. Smolin, Y.F. Shepelev, D. Gyepesová, P. Schwendt, Acta Crystallogr. C45, 1477 (1989)
  • [48] A.E. Lapshin, Y.I. Smolin, Y.F. Shepelev, P. Schwendt, D. Gyepesová, Acta Crystallogr. C46, 738 (1990)
  • [49] J. Podlahová, J. Loub, F. Pechar, V. Petříček, Acta Crystallogr. C40, 1999 (1984)
  • [50] D. Begin, F.W.B. Einstein, J. Field, Inorg. Chem. 8, 1785 (1975) http://dx.doi.org/10.1021/ic50150a009[Crossref]
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-013-0266-8
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