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2013 | 11 | 8 | 1352-1359
Tytuł artykułu

The first transition metal iodato peroxido complex: the synthesis, vibrational spectra and crystal structure from powder diffraction data of K3[V2O2(O2)4(IO3)]·H2O

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Języki publikacji
EN
Abstrakty
EN
The first transition metal iodato peroxido complex, K3[V2O2(O2)4(IO3)]·H2O (I), was prepared by crystallization from the KVO3 - KIO3 - H2O2 - H2O - ethanol (HNO3) solution. The dinuclear anion is immediately decomposed in aqueous solution; the 51V NMR spectrum exhibits signals corresponding to [VO(O2)2(H2O)]−, [V2O2(OH)(O2)4]3− and H2VO4− species only. The IR and Raman spectra contain all characteristic bands of the VO(O2)2 group and the coordinated IO3− ligand. Based on the positions of bands assigned to the vibrations of the VO(O2)2 groups a pentagonal pyramidal arrangement around the vanadium atoms can be supposed. The crystal structure was solved from X-ray synchrotron powder data by direct space method and refined by energy minimization in the solid state employing a hybrid PBE0 functional. This crystal and molecular structure, has confirmed the presence of hexacoordinated vanadium atoms and revealed asymmetric dinuclear structure of the [V2O2(O2)4(IO3)]3− ion. The coordination spheres of vanadium atoms are different - the IO3− anion is coordinated only to one vanadium center. A thermal analysis of the complex confirmed the presence of water molecules in the crystal structure and revealed a considerable stability of the dehydrated complex. [...]
Wydawca

Czasopismo
Rocznik
Tom
11
Numer
8
Strony
1352-1359
Opis fizyczny
Daty
wydano
2013-08-01
online
2013-06-01
Twórcy
  • Department of Inorganic Chemistry, Faculty of Natural Sciences, Comenius University in Bratislava, 842 15, Bratislava 4, Slovak Republic
  • Department of Inorganic Chemistry, Faculty of Natural Sciences, Comenius University in Bratislava, 842 15, Bratislava 4, Slovak Republic
  • Department of Inorganic Chemistry, Faculty of Natural Sciences, Comenius University in Bratislava, 842 15, Bratislava 4, Slovak Republic, chrappova@fns.uniba.sk
  • Institute of Inorganic Chemistry, Slovak Academy of Sciences, SK-845 36, Bratislava, Slovak Republic
  • Laboratory of Crystallography, DPMC-MaNEP, University of Geneva, CH-1211, Geneva, Switzerland
autor
  • Swiss-Norwegian Beam Lines at ESRF, BP-220, 38043, Grenoble, France
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-013-0266-8
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