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2013 | 11 | 6 | 1001-1009
Tytuł artykułu

Synthesis and characterization of 2CuCN·DMSO and [CuII(DMSO)6][CuI 6(CN)8] 3-D framework compounds

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Two novel complexes of CuCN were characterized by using a single-crystal X-ray diffraction technique and Raman spectroscopy. In the structure of 2CuCN·DMSO ligand molecule demonstrates unique bridging mode, being bound to two CuI centers via oxygen and sulfur atoms. The bridging role of both CN groups and DMSO molecules results in the formation of (CuCN·DMSO)n framework. Along the channels of the network are running infinite zig-zag (CuCN)n chains, which are bound to the framework by elongated Cu…(CN) bonds. A mixed-valence [CuII(DMSO)6][CuI 6(CN)8] compound is composed of 3-D [CuI 6(CN)8]n anionic framework and located in the channels of partially disordered [CuII(DMSO)6]2+ cations.
Wydawca

Czasopismo
Rocznik
Tom
11
Numer
6
Strony
1001-1009
Opis fizyczny
Daty
wydano
2013-06-01
online
2013-03-28
Twórcy
  • Department of Inorganic Chemistry and Technology, Institute Jožef Stefan, 1000, Ljubljana, Slovenia, andrii.vakulka@ijs.si
  • Department of Inorganic Chemistry and Technology, Institute Jožef Stefan, 1000, Ljubljana, Slovenia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-013-0232-5
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