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2013 | 11 | 6 | 979-987
Tytuł artykułu

Debromination of 2,4,6-tribromophenol coupled with biodegradation

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The application effect of aluminium and their alloys and mixtures with nickel was studied for the complete hydrodebromination of 2,4,6-tribromophenol (TBP) to phenol in aqueous NaOH solution at room temperature. It was found that the Raney Al-Ni alloy can rapidly transform TBP to phenol. Removal efficiency of 25 mM TBP solution in aqueous NaOH (15 g L−1) solution at the end of 1h reaction was 100% using 4 g L−1 Al-Ni. The hydrodebromination is accompanied by the dissolution of aluminium and formation of soluble Al(OH)4−1 anions under these reaction conditions. After completion of the hydrodebromination reaction removal of the dissolved metals was achieved by precipitation of appropriate hydroxides by adjustment of the pH value and filtration, the filtrate was treated with Pseudomonas or Rhodococcus bacterial strains to degrade dissolved phenol. The combined application of both (chemical-biological) treatments produced degradations of 100% of aromatic compounds. [...]
Wydawca

Czasopismo
Rocznik
Tom
11
Numer
6
Strony
979-987
Opis fizyczny
Daty
wydano
2013-06-01
online
2013-03-28
Twórcy
  • Institute of Environmental and Chemical Engineering, Faculty of Chemical Technology, University of Pardubice, 532 10, Pardubice, Czech Republic, tomas.weidlich@upce.cz
  • Department of Biotechnology, Institute of Chemical Technology Prague, 166 28, Prague 6, Czech Republic
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-013-0231-6
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