Applicability of Gd-doped BaZrO3, SrZrO3, BaCeO3 and SrCeO3 proton conducting perovskites as electrolytes for solid oxide fuel cells

• Autorzy: Wojciech Zając , Dariusz Rusinek , Kun Zheng , Janina Molenda
• Języki publikacji: EN

Abstrakty

EN

Four proton conducting oxides of perovskite structure: BaZrO3, SrZrO3, BaCeO3 and SrCeO3 doped with 5 mol.% of gadolinium are compared in terms of crystal structure, microstructure, sinterability, water sorption ability, ionic transference number, electrical conductivity and stability towards CO2. Relations between proton conductivity, structural and chemical parameters: pseudo-cubic unit cell volume, lattice free volume, tolerance factor, crystal symmetry and electronegativity are discussed. The grain boundary resistance is shown to be the limiting factor of total proton-conductivity for the materials examined. The highest proton conductivity was observed for BaCeO3, however, it turned out to be prone to degradation in CO2-containing atmosphere and reduction at high temperatures. On the other hand, Ba and Sr zirconates are found to be more chemically stable, but exhibit low electrical conductivity. Electrical conductivity relaxation upon hydration is used to calculate proton diffusion coefficient. Selected materials were tested as electrolytes in solid oxide fuel cells. [...]

Słowa kluczowe

EN

Solid oxide fuel cells; Crystal structure; Proton conductivity; Conductivity relaxation; Stability towards CO2

• Czasopismo: Open Chemistry
• Rocznik: 2013
• Tom: 11
• Numer: 4
• Strony: 471-484

Daty

wydano

2013-04-01

online

2013-01-23

Twórcy

autor

Wojciech Zając

• Department of Hydrogen Energy, Faculty of Energy and Fuels, AGH University of Science and Technology, 30-059, Kraków, Poland,

autor

Dariusz Rusinek

• Department of Hydrogen Energy, Faculty of Energy and Fuels, AGH University of Science and Technology, 30-059, Kraków, Poland

autor

Kun Zheng

• Department of Hydrogen Energy, Faculty of Energy and Fuels, AGH University of Science and Technology, 30-059, Kraków, Poland

autor

Janina Molenda

• Department of Hydrogen Energy, Faculty of Energy and Fuels, AGH University of Science and Technology, 30-059, Kraków, Poland

Bibliografia

• [1] S. Srinivasan, Fuel Cells. From Fundamentals to Applications (Springer Science+Business Media, LLC, New York, USA, 2006)
• [2] N.Q. Minh, Solid State Ionics 174, 271 (2004) http://dx.doi.org/10.1016/j.ssi.2004.07.042[Crossref]
• [3] S.M. Haile, Acta Mater. 51, 5981 (2003) http://dx.doi.org/10.1016/j.actamat.2003.08.004[Crossref]
• [4] J. Molenda, K. Świerczek, W. Zając, J. Power Sources 173, 657 (2007) http://dx.doi.org/10.1016/j.jpowsour.2007.05.085[Crossref]
• [5] N. Ito, M. Iijima, K. Kimura, S. Iguchi, J. Power Sources 152, 200 (2005) http://dx.doi.org/10.1016/j.jpowsour.2005.01.009[Crossref]
• [6] S. Song, E.D. Wachsman, S.E. Dorris, U. Balachandran, In: E.D. Wachsman, K.S. Lyons, M. Carolyn, F. Garzon, M. Liu (Eds.), Solid State Ionic Devices III (The Electrochemical Society Inc., Pennington, NJ, USA, 2003) 456
• [7] H. Iwahara, T. Esaka, H. Uchida, N. Maeda, Solid State Ionics 3–4, 359 (1981) http://dx.doi.org/10.1016/0167-2738(81)90113-2[Crossref]
• [8] H. Iwahara, H. Uchida, K. Ono, K. Ogaki, J. Electrochem. Soc. 135, 529 (1988) http://dx.doi.org/10.1149/1.2095649[Crossref]
• [9] H. Iwahara, Solid State Ionics 77, 289 (1995) http://dx.doi.org/10.1016/0167-2738(95)00051-7[Crossref]
• [10] H. Iwahara, Solid State Ionics 86-88, 9 (1996) http://dx.doi.org/10.1016/0167-2738(96)00087-2[Crossref]
• [11] H. Iwahara, T. Shimura, H. Matsumoto, Electrochemistry 68, 154 (2000)
• [12] K.D. Kreuer, E. Schönherr, J. Maier, Solid State Ionics 70-71, 278 (1994) http://dx.doi.org/10.1016/0167-2738(94)90323-9[Crossref]
• [13] A.S. Nowick, Y. Du, Solid State Ionics 77, 137 (1995) http://dx.doi.org/10.1016/0167-2738(94)00230-P[Crossref]
• [14] K.D. Kreuer, Solid State Ionics 97, 1 (1997) http://dx.doi.org/10.1016/S0167-2738(97)00082-9[Crossref]
• [15] S. Wienströer, H.-D. Wiemhöfer, Solid State Ionics 101–103, 1113 (1997) http://dx.doi.org/10.1016/S0167-2738(97)00163-X[Crossref]
• [16] K.D. Kreuer, Solid State Ionics 125, 285 (1999) http://dx.doi.org/10.1016/S0167-2738(99)00188-5[Crossref]
• [17] T. Norby, Solid State Ionics 125, 1 (1999) http://dx.doi.org/10.1016/S0167-2738(99)00152-6[Crossref]
• [18] K.D. Kreuer, Annu. Rev. Mater. Res. 33, 333 (2003) http://dx.doi.org/10.1146/annurev.matsci.33.022802.091825[Crossref]
• [19] T. Norby, M. Widerøe, R. Glöckner, Y. Larring, Dalton Trans. 3012 (2004) [Crossref]
• [20] L. Malavasi, C.A.J. Fisher, M.S. Islam, Chem. Soc. Rev. 39, 4370 (2010) http://dx.doi.org/10.1039/b915141a[Crossref]
• [21] Y. Yamazaki, C.-K. Yang, S.M. Haile, Scripta Mater. 65, 102 (2011) http://dx.doi.org/10.1016/j.scriptamat.2010.12.034[Crossref]
• [22] W. Münch, G. Seifert, K.D. Kreuer, J. Maier Solid State Ionics 86-88, 647 (1996) http://dx.doi.org/10.1016/0167-2738(96)00229-9[Crossref]
• [23] Y. Larring, T. Norby, Solid State Ionics 77, 147 (1995) http://dx.doi.org/10.1016/0167-2738(94)00261-P[Crossref]
• [24] K.H. Ryu, S.M. Haile, Solid State Ionics 125, 355 (1999) http://dx.doi.org/10.1016/S0167-2738(99)00196-4[Crossref]
• [25] N. Taniguchi, K. Natoh, J. Niikura, T. Gamo, Solid State Ionics 53-56, 998 (1992) http://dx.doi.org/10.1016/0167-2738(92)90283-U[Crossref]
• [26] S.J. Stokes, M.S. Islam, J. Mater. Chem., 20, 6258 (2010) http://dx.doi.org/10.1039/c0jm00328j[Crossref]
• [27] F. Giannici, A. Longo, A. Balerna, A. Martorana, Chem. Mater. 21, 597 (2009) http://dx.doi.org/10.1021/cm8029888[Crossref]
• [28] A.C. Larson, R.B. Von Dreele, Los Alamos National Laboratory Report LAUR 86-748 (2004)
• [29] B.H. Toby, J. Appl. Cryst. 34, 210 (2001) http://dx.doi.org/10.1107/S0021889801002242[Crossref]
• [30] M. Mogensen, D. Lybye, N. Bonanos, P.V. Hendriksen, F.W. Poulsen, Solid State Ionics 174, 279 (2004) http://dx.doi.org/10.1016/j.ssi.2004.07.036[Crossref]
• [31] W. Zając, J. Molenda, Solid State Ionics 192, 163 (2011) http://dx.doi.org/10.1016/j.ssi.2010.05.025[Crossref]
• [32] S.M. Haile, D.L. West, J. Campbell, J. Mater. Res. 13, 1576 (1998) http://dx.doi.org/10.1557/JMR.1998.0219[Crossref]
• [33] E. Barsoukov, J.R. Macdonald, Impedance Spectroscopy. Theory, Experiment, and Applications, 2nd edition (John Wiley & Sons, Inc., Hoboken, New Jersey, USA, 2005) http://dx.doi.org/10.1002/0471716243[Crossref]
• [34] A.S. Nowick, A.V. Vaysleyb, Solid State Ionics 97, 17 (1997) http://dx.doi.org/10.1016/S0167-2738(97)00081-7[Crossref]
• [35] J. Wu, L.P. Li, W.T.P. Espinosa, S.M. Haile, J. Mater. Res. 19, 2366 (2004) http://dx.doi.org/10.1557/JMR.2004.0302[Crossref]
• [36] A. Braun, S. Duval, P. Ried, J. Embs, F. Juranyi, T. Strässle, U. Stimming, R. Hempelmann, P. Holtappels, T. Graule, J. Appl. Electrochem. 39, 471 (2009) http://dx.doi.org/10.1007/s10800-008-9667-3[Crossref]
• [37] T. Schober, J. Friedrich, J.B. Condon, Solid State Ionics 77, 175 (1995) http://dx.doi.org/10.1016/0167-2738(94)00269-X[Crossref]
• [38] V.P. Gorelov, V.B. Balakireva, Yu.N. Kleshchev, V.P. Brusentsov, Inrog. Mater. 37, 535 (2001) http://dx.doi.org/10.1023/A:1017553506634[Crossref]
• [39] H. Iwahara, T. Yajima, T. Hibino, K. Ozaki, H. Suzuki, Solid State Ionics 61, 65 (1993) http://dx.doi.org/10.1016/0167-2738(93)90335-Z[Crossref]
• [40] K. Katahira, Y. Kohcchi, T. Shimura, H. Iwahara, Solid State Ionics 138, 91 (2000) http://dx.doi.org/10.1016/S0167-2738(00)00777-3[Crossref]
• [41] C. Chen, G. Ma, J. Alloy. Compd. 485, 69 (2009) http://dx.doi.org/10.1016/j.jallcom.2009.05.108[Crossref]
• [42] D.A. Stevenson, N. Jiang, R.M. Buchanan, F.E.G. Henn, Solid State Ionics 62, 279 (1993) http://dx.doi.org/10.1016/0167-2738(93)90383-E[Crossref]
• [43] S. Okada, A. Mineshige, M. Kobune, T. Yazawa, J. Ceram. Soc. Jap. 112, S700 (2004)
• [44] X. Qi, Y.S. Lin, Solid State Ionics 130, 149 (2000) http://dx.doi.org/10.1016/S0167-2738(00)00281-2[Crossref]
• [45] T. Shimura, H. Tanaka, H. Matsumoto, T. Yogo, Solid State Ionics 176, 2945 (2005) http://dx.doi.org/10.1016/j.ssi.2005.09.027[Crossref]
• [46] J. Dauter, N. Maffei, S.S. Bhella, V. Thangadurai, J. Electrochem. Soc. 157, B1413 (2010) http://dx.doi.org/10.1149/1.3464774[Crossref]
• [47] F. Zhao, Q. Liu, S. Wang, K. Brinkman, F. Chen, Int. J. Hydrogen Energ. 35, 4258 (2010) http://dx.doi.org/10.1016/j.ijhydene.2010.02.080[Crossref]
• [48] C. Zhang, H. Zhao, Solid State Ionics 206, 17 (2012) http://dx.doi.org/10.1016/j.ssi.2011.10.026[Crossref]
• [49] S. Tao, J.T.S. Irvine, Adv. Mater. 18, 1581 (2006) http://dx.doi.org/10.1002/adma.200502098[Crossref]
• [50] E. Fabbri, I. Markus, L. Bi, D. Pergolesi, E. Traversa, Solid State Ionics 202, 30 (2011) http://dx.doi.org/10.1016/j.ssi.2011.08.019[Crossref]
• [51] L. Yang, S. Wang, K. Blinn, M. Liu, Z. Liu, Z. Cheng, M. Liu, Science 326, 126 (2009) http://dx.doi.org/10.1126/science.1174811[Crossref]
• [52] W. Münich, K.D. Kreuer, S. Adams, G. Seifert, J. Maier, Phase Transit. 68, 567 (1999) http://dx.doi.org/10.1080/01411599908224535[Crossref]
• [53] J.-H. Yu, J.-S. Lee, J. Maier, Solid State Ionics 181, 154 (2010) http://dx.doi.org/10.1016/j.ssi.2009.11.003[Crossref]
• [54] J.-H. Yu, J.-S. Lee, J. Maier, Angew. Chem. Int. Ed. 46, 8992 (2007) http://dx.doi.org/10.1002/anie.200701765[Crossref]
• [55] H.-I. Yoo, J.-K. Kim, C.-E. Lee, J. Electrochem. Soc. 156, B66 (2009) http://dx.doi.org/10.1149/1.3005981[Crossref]
• [56] H.-I. Yoo, J.I. Yeon, J.-K. Kim, Solid State Ionics 180, 1443 (2009) http://dx.doi.org/10.1016/j.ssi.2009.09.006[Crossref]
• [57] H.-I. Yoo, J.-Y. Yoon, J.-S. Ha, C.-E. Lee, Phys. Chem. Chem. Phys. 10, 974 (2008) http://dx.doi.org/10.1039/b709371c[Crossref]
• [58] D.-K. Lim, M.-B. Choi, K.-T. Lee, H.-S. Yoon, E. D. Wachsman, S.-J. Song, J. Electrochem. Soc., 158, B852 (2011) http://dx.doi.org/10.1149/1.3597634[Crossref]
• [59] J. Crank, The Mathematics of Diffusion (Clarendon Press, Oxford, UK, 1975)

Identyfikatory

DOI

10.2478/s11532-012-0144-9