Potassium trans-[bis(oxalato)diaquacobaltate(II)] tetrahydrate: synthesis, structure, potentiometric and thermal studies

• Autorzy: Agnieszka Chylewska , Artur Sikorski , Aleksandra Dąbrowska , Lech Chmurzyński
• Języki publikacji: EN

Abstrakty

EN

The title compound, trans-K2[Co(C2O4)2(H2O)2]·4H2O, was synthesised, and characterised by elemental analysis. Acid dissociation constants for the complex were determined by potentiometric titration and calculated by STOICHIO program. The crystal structure of trans-K2[Co(C2O4)2(H2O)2]·4H2O was determined by X-ray diffraction studies. The asymmetric part of the unit cell contains one symmetric anion of oxalate and water molecule bound with Co(II) ion in crystallographic special position, one potassium cation and two molecules of water. Thermal properties of the complex were examined by thermogravimetric analysis (TGA). A decomposition mechanism is proposed on the basis of the results.

Słowa kluczowe

EN

Cobalt(II) complex; Oxalate ligands; X-ray; Thermogravimetry; Potentiometry

• Czasopismo: Open Chemistry
• Rocznik: 2013
• Tom: 11
• Numer: 1
• Strony: 8-15

Daty

wydano

2013-01-01

online

2012-10-24

Twórcy

autor

Agnieszka Chylewska

• University of Gdańsk,

autor

Artur Sikorski

• University of Gdańsk

autor

Aleksandra Dąbrowska

• University of Gdańsk

autor

Lech Chmurzyński

• University of Gdańsk

Bibliografia

• [1] P.J. Sadler, Struct. Bond. 29, 171 (1984) http://dx.doi.org/10.1007/BFb0116521[Crossref]
• [2] J.A. Cowan, Inorganic Biochemistry, 2nd edition (Wiley-VCH: New York, 1997)
• [3] M.J.E. Clark, Ruthenium and Other Metal Complexes in Cancer Chemotherapy (Springer-Verlag, Heidelberg, Germany, 1989)
• [4] I. Bertini, H.B. Gray, E.I. Stiefel, J.S. Valentine, Biological Inorganic Chemistry: Structure and Reactivity (University Science Books, Sausalito, USA, 2007)
• [5] M. Kobayashi, S. Shimizu, Eur. J. Biochem. 261, 1 (1999) http://dx.doi.org/10.1046/j.1432-1327.1999.00186.x[Crossref]
• [6] T. Takeuchi, A. Böttcher, C.M. Quezada, T.J. Meade, H.B. Gray, Bioorg. Med. Chem. 7, 815 (1999) http://dx.doi.org/10.1016/S0968-0896(98)00272-7[Crossref]
• [7] J.A. Schwartz, E.K. Lium, S.J. Silverstein, J. Virol. 75, 4117 (2001) http://dx.doi.org/10.1128/JVI.75.9.4117-4128.2001[Crossref]
• [8] S.P. Epstein, Y.Y. Pashinsky, D. Gershon, I. Winicov, C. Srivilasa, K.J. Kristic, P.A. Asbell, BMC Opthalmol. 6, 22 (2006) http://dx.doi.org/10.1186/1471-2415-6-22[Crossref]
• [9] R. Selvam, K. Kannabiran, J. Urology 156, 237 (1996) http://dx.doi.org/10.1016/S0022-5347(01)66008-7[Crossref]
• [10] M. Yashiro, M. Komiyama, K. Kuroda, S. Miura, S. Yoshikawa, S. Yano, Bull. Chem. Soc. Jpn. 67, 3276 (1994) http://dx.doi.org/10.1246/bcsj.67.3276[Crossref]
• [11] J. Glerup, P.A. Goodson, D.J. Hodgson, K. Michelsen, Inorg. Chem. 34, 6255 (1995) http://dx.doi.org/10.1021/ic00129a009[Crossref]
• [12] V. Jordanovska, R. Trojko, Thermochim. Acta 258, 205 (1995) http://dx.doi.org/10.1016/0040-6031(94)02243-H[Crossref]
• [13] M.R. Ullah, P.K. Bhattacharya, K. Venkatasubramanian, Polyhedron 22, 4025 (1996) http://dx.doi.org/10.1016/0277-5387(96)00132-5[Crossref]
• [14] V. Vallet, H. Moll, U. Wahlgren, Z. Szabó, I. Grenthe, Inorg. Chem. 25, 8598 (2003) http://dx.doi.org/10.1021/ic035223f[Crossref]
• [15] V. Vallet, H. Moll, U. Wahlgren, Z. Szabó, I. Grenthe, Inorg. Chem. 6, 1982 (2003) http://dx.doi.org/10.1021/ic026068s[Crossref]
• [16] H.Z. Kou, O. Sato, Inorg. Chem. 23, 9513 (2007) http://dx.doi.org/10.1021/ic701043f[Crossref]
• [17] M. Clemente-León, E. Coronado, M. López-Jordà, J. C. Waerenborgh, Inorg. Chem. 18, 9122 (2011) http://dx.doi.org/10.1021/ic201293f[Crossref]
• [18] Clare E. Rowland and Christopher L. Cahill, Inorg. Chem. 14, 6716 (2010) http://dx.doi.org/10.1021/ic100887c[Crossref]
• [19] G.T. Webster, D. McNaughton, B.R. Wood, J. Phys. Chem. Sec. B 113, 6910 (2009) http://dx.doi.org/10.1021/jp811028a[Crossref]
• [20] J.J.G. Icki, U.S. patent 2,748,069 (May 29, 1956)
• [21] K.V. Krishnamurty, G.M. Harris, Chem. Rev. 61, 213 (1961) http://dx.doi.org/10.1021/cr60211a001[Crossref]
• [22] D.D. Campano, E.R. Kantrowitz, M.Z. Hoffman, M.S. Weinberk, J. Phys. Chem. 78, 686 (1974) http://dx.doi.org/10.1021/j100600a008[Crossref]
• [23] J.C. Scaiano, W.J. Leigh, G. Ferraudi, Can. J. Chem. 62, 2355 (1984) http://dx.doi.org/10.1139/v84-403[Crossref]
• [24] E.R. Kantrowitz, M.Z. Hoffman, J.F. Endicott, J. Phys. Chem. 75, 1914 (1971) http://dx.doi.org/10.1021/j100682a003[Crossref]
• [25] A.F. Vaudo, E.R. Kantrowitz, M.Z. Hoffman, J. Am. Chem. Soc. 93, 6698 (1971) http://dx.doi.org/10.1021/ja00753a074[Crossref]
• [26] A.L. Poznyak, V.I. Pavlovski, E.B. Chuklannova, T.N. Polynova, M.A. Porai-Koshits, Monatsh. Chem. 113, 561 (1982) http://dx.doi.org/10.1007/BF00800262[Crossref]
• [27] A. Dąbrowska, D. Jacewicz, A. Łapińska, B. Banecki, A. Figarski, M. Szkatuła, L. Lehman, J. Krajewski, J. Kubasik-Juraniec, M. Woźniak, L. Chmurzyński, Biochem. Biophys. Res. Comm. 326, 313 (2005) http://dx.doi.org/10.1016/j.bbrc.2004.11.032[Crossref]
• [28] D. Jacewicz, A. Dąbrowska, A. Łapińska, A. Figarski, M. Woźniak, L. Chmurzyński Anal. Biochem. 350, 256 (2006) http://dx.doi.org/10.1016/j.ab.2005.12.016[Crossref]
• [29] D. Jacewicz, A. Dąbrowska, A. Łapińska, M. Woźniak, L. Chmurzyński, Trans. Met. Chem. 31, 1045 (2006) http://dx.doi.org/10.1007/s11243-006-0107-0[Crossref]
• [30] H. Okazaki, Y. Kushi, H. Yoneda, J. Am.Chem. Soc. 107, 4183 (1985) http://dx.doi.org/10.1021/ja00300a017[Crossref]
• [31] Kuma KM-4 Software User’s Guide, Version 3.1. (Kuma Diffraction, Wrocław, Poland, 1989)
• [32] G.M. Sheldrick, Acta Cryst. A64, 112 (2008)
• [33] G.M. Sheldrick, SHELXL, Program for crystal structure refinement (University of Göttingen, Germany, 1997)
• [34] A.I. Vogel, Vogel’s textbook of quantitative inorganic analysis, 4th edition (Longman, London, 1978)
• [35] J. Kostrowicki, A. Liwo, Comp. Chem. 8, 91 (1984) http://dx.doi.org/10.1016/0097-8485(84)85002-0[Crossref]
• [36] J. Kostrowicki, A. Liwo, Comp. Chem. 11, 195 (1987) http://dx.doi.org/10.1016/0097-8485(87)80018-9[Crossref]
• [37] J. Kostrowicki, A. Liwo, Talanta 37, 645 (1990) http://dx.doi.org/10.1016/0039-9140(90)80211-W[Crossref]
• [38] Ł. Gurzyński, A. Puszko, M. Makowski, J. Makowska, L. Chmurzyński, J. Chem. Thermodyn. 38, 554 (2006) http://dx.doi.org/10.1016/j.jct.2005.07.005[Crossref]
• [39] Ł. Gurzyński, A. Puszko, M. Makowski, L. Chmurzyński, J. Chem. Thermodyn. 39, 1272 (2007) http://dx.doi.org/10.1016/j.jct.2007.01.014[Crossref]
• [40] D.W. Marquard, J. Applied Math. 11, 431 (1963)
• [41] E. Kaczmarczyk, K. Maj, L. Chmurzyński, J. Chem. Thermod. 32, 901 (2000) http://dx.doi.org/10.1006/jcht.2000.0664[Crossref]
• [42] C.K. Johnson, ORTEP II; Report ORNL-5138 (Oak Ridge National Laboratory, Oak Ridge, USA, 1976)
• [43] J.P. Garcia-Teran, O. Castillo, A. Luque, U. Garcia-Couceiro, G. Beobide, P. Roman, Cryst. Growth Des. 7, 2594 (2007) http://dx.doi.org/10.1021/cg0705916[Crossref]
• [44] P. Roman, C. Guzman-Miralles, A. Luque, Acta Crystallogr., Cryst. Struct. Comm. C49, 1336 (1993)
• [45] W.S. Benedict, N. Gailar, E.K. Plyler, J. Chem. Phys. 24, 1139 (1956) http://dx.doi.org/10.1063/1.1742731[Crossref]
• [46] J.H. Taylor, W.S. Benedict, J. Strong, J. Chem. Phys. 20, 1884 (1952) http://dx.doi.org/10.1063/1.1700332[Crossref]
• [47] A.E. Martell, R.J. Motekaitis, The determination and use of stability constants, 2nd edition (VCH, New York, 1992) chapter 3

Identyfikatory

DOI

10.2478/s11532-012-0129-8