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2012 | 10 | 6 | 1933-1941
Tytuł artykułu

Extraction properties of β-aminophosphine oxides towards lanthanides and alkaline earth metals

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The investigation of the extraction properties of a series of polyoligodentate β-aminophosphine oxides 1–8 bearing from one to six phosphine oxide groups in a molecule towards Ln(III) and alkaline earth metals ions from neutral media has revealed that, using common diluents, the extraction efficiency increases with an increase of a number of P=O functions in a ligand. The addition of ionic liquid, namely 1-butyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide ([bmim][NTf2]), significantly increasing the extraction efficiency and application of IL concentration of 0.05 M (in 1,2-dichloroethane) providing the maximum recovery of metal ions with Lu/La separation factor reaching up to 91. Hexapodal tris[bis(2-diphenylphosphorylethyl)aminoethyl]amine 8 demonstrates the highest extraction under all conditions applied and the separation factor for U and Eu of this compound exceeded 103. [...]
Wydawca
Czasopismo
Rocznik
Tom
10
Numer
6
Strony
1933-1941
Opis fizyczny
Daty
wydano
2012-12-01
online
2012-09-21
Twórcy
  • A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russia , matveeva@gmail.com
  • A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russia
  • Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, 142432, Russia
  • Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences, Chernogolovka, 142432, Russia
  • A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russia
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-012-0124-0
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