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2012 | 10 | 4 | 1338-1348
Tytuł artykułu

Thermo-responsiveness of polysiloxanes grafted with poly(dimethyl acrylamide) segments

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Thermo-sensitive polymers are of outstanding importance due to their ability to undergo controlled major changes in their properties as a response to minor modifications in temperature. The syntheses of novel polymers by grafting polysiloxane containing chlorobenzyl groups in the side chain by the homopolymerization of N,N′-dimethyl acrylamide (DMA) or the copolymerization of DMA and methyl methacrylate (MMA) using SET-LRP technique are presented. The polymers were characterized by 1H-NMR, UV, and fluorescence spectroscopy, and DSC. The thermo-sensitivity and the lower critical solution temperature (LCST), as well as the aggregation phenomena during the phase transition are evidenced by dynamic light scattering (DLS) and rheology. [...]
Wydawca

Czasopismo
Rocznik
Tom
10
Numer
4
Strony
1338-1348
Opis fizyczny
Daty
wydano
2012-08-01
online
2012-05-29
Twórcy
  • Department of Natural and Synthetic Polymers, «Gheorghe Asachi» Technical University of Iasi, 700050, Iasi, Romania
  • LIST Saclay, Laboratoire Capteurs et Architectures Électroniques, CEA, F-91191, Gif-sur-Yvette Cedex, France
  • Department of Natural and Synthetic Polymers, «Gheorghe Asachi» Technical University of Iasi, 700050, Iasi, Romania, nhurduc@ch.tuiasi.ro
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-012-0061-y
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