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Czasopismo
2012 | 10 | 4 | 1218-1222
Tytuł artykułu

Diironcarbonyl-coumarin complex: preparation, intramolecular electron transfer, and electro-generation of hydrogen

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
A new organometallic complex coupling photoactive coumarin to a diironhexacarbonyl unit has been successfully prepared and its composition and electronic structure confirmed by elemental and spectroscopic analyses. Emission spectral analysis of the complex reveals photoinduced intramolecular electron transfer from coumarin to the iron-carbonyl moiety. The compound is electrochemically reduced at −1.24 V vs. Fc/Fc+. This reduction is irreversible, attesting to the instability of the complex. Electrochemical evolution of hydrogen in the presence of the complex has been studied and results are discussed. [...]
Wydawca

Czasopismo
Rocznik
Tom
10
Numer
4
Strony
1218-1222
Opis fizyczny
Daty
wydano
2012-08-01
online
2012-05-29
Twórcy
autor
  • Department of Physical Sciences, Arkansas Tech University, Russellville, Arkansas, 72801, USA, cmebi@atu.edu
  • Department of Physical Sciences, Arkansas Tech University, Russellville, Arkansas, 72801, USA
  • Department of Physical Sciences, Arkansas Tech University, Russellville, Arkansas, 72801, USA
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-012-0048-8
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