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Czasopismo
2011 | 9 | 6 | 1143-1149
Tytuł artykułu

Ternary ion-association complexes between the indium(III) - 4-(2-pyridylazo)resorcinol anionic chelate and some tetrazolium cations

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Complex formation and liquid-liquid extraction were studied in systems containing indium(III), 4-(2-pyridylazo)resorcinol (PAR), tetrazolium salt (TZS), water and chloroform. Two different TZS were used: 2,3,5-triphenyl-2H-tetrazolium chloride (TTC) and 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl-2H-tetrazolium bromide (MTT). The optimum conditions for extraction of In(III) as a ternary complex, (TT+)[In(PAR)2] or (MTT+)[In(PAR)2], were found: pH, extraction time, concentration of PAR and concentration of TZS. The constants of extraction (Kex), constants of association (β), constants of distribution (KD) and recovery factors (R%) were determined. The apparent molar absorptivities in chloroform were calculated to be ɛ′520=6.6×104 L mol−1 cm−1 and ɛ′515=7.1×104 L mol−1 cm−1 for the systems with TTC (I) and MTT (II), respectively. Beer’s law was obeyed for In(III) concentrations up to 3.4 µg mL−1 in both the cases. The limits of detection (LOD=0.07 µg mL−1I and LOD=0.12 µg mL−1II), limits of quantification (LOQ=0.24 µg mL−1I and LOQ=0.41 µg mL−1II) and Sandell’s sensitivities (SS) were estimated as well. [...]
Wydawca

Czasopismo
Rocznik
Tom
9
Numer
6
Strony
1143-1149
Opis fizyczny
Daty
wydano
2011-12-01
online
2011-09-27
Twórcy
  • Department of General and Inorganic Chemistry, University of Plovdiv, 4000, Plovdiv, Bulgaria
  • Department of General and Inorganic Chemistry, University of Plovdiv, 4000, Plovdiv, Bulgaria, kgavazov@abv.bg
autor
  • Department of General and Inorganic Chemistry, University of Plovdiv, 4000, Plovdiv, Bulgaria
  • Department of General and Inorganic Chemistry, University of Plovdiv, 4000, Plovdiv, Bulgaria
  • Department of General and Inorganic Chemistry, University of Plovdiv, 4000, Plovdiv, Bulgaria
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-011-0101-z
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