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2011 | 9 | 6 | 990-999
Tytuł artykułu

Ruthenium(II)-bis(4′-(4-ethynylphenyl)-2,2′:6′, 2″-terpyridine) - A versatile synthon in supramolecular chemistry. Synthesis and characterization

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
A homoleptic ethynyl-substituted ruthenium(II)-bisterpyridine complex representing a versatile synthon in supramolecular chemistry was synthesized and analyzed by NMR spectroscopy, mass spectrometry and X-ray diffractometry. Furthermore, its photophysical properties were detailed by UV/Vis absorption, emission and resonance Raman spectroscopy. In order to place the results obtained in the context of the vast family of ruthenium coordination compounds, two structurally related complexes were investigated accordingly. These reference compounds bear either no or an increased chromophore in the 4′-position. The spectroscopic investigations reveal a systematic bathochromic shift of the absorption and emission maximum upon increasing chromophore size. This bathochromic shift of the steady state spectra occurs hand in hand with increasing resonance Raman intensities upon excitation of the metal-to-ligand charge-transfer transition. The latter feature is accompanied by an increased excitation delocalization over the chromophore in the 4′-position of the terpyridine. Thus, the results presented allow for a detailed investigation of the electronic effects of the ethynyl substituent on the metal-to-ligand charge-transfer states in the synthon for click reactions leading to coordination polymers. [...]
Słowa kluczowe
Wydawca

Czasopismo
Rocznik
Tom
9
Numer
6
Strony
990-999
Opis fizyczny
Daty
wydano
2011-12-01
online
2011-09-27
Twórcy
  • Institute for Physical Chemistry, Jena Center for Soft Matter (JCSM), and Abbe Center of Photonics (ACP) Friedrich-Schiller-University Jena, 07743, Jena, Germany
  • Laboratory of Organic and Macromolecular Chemistry (IOMC) and Jena Center for Soft Matter (JCSM) Friedrich-Schiller-University Jena, 07743, Jena, Germany
  • Laboratory of Organic and Macromolecular Chemistry (IOMC) and Jena Center for Soft Matter (JCSM) Friedrich-Schiller-University Jena, 07743, Jena, Germany
  • Institute for Physics, Ilmenau University of Technology, 98693, Ilmenau, Germany
  • Laboratory of Inorganic and Analytical Chemistry, Friedrich-Schiller-University Jena, 07743, Jena, Germany
autor
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-011-0087-6
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