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2011 | 9 | 5 | 776-789
Tytuł artykułu

Analysis of crystallographic and structural data of polymeric FeM (M = transition metals, lanthanides) complexes

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
This review covers crystallographic and structural data for almost fifty polymeric FeM complexes (M = transition Cu, Ag, Au, Mo, W, Mn, Co, Ni and Pt and lanthanide elements Sm, Er and Yb) where iron is involved in polymeric chains. The complexes are for the most part yellow or black, but there are complexes of brown, orange, red, purple, blue and green colour. The complexes crystallized in the monoclinic (by far prevails), triclinic, tetragonal, orthorhombic, trigonal, hexagonal and rhombohedral crystal classes. The iron atoms are found in oxidation states 0, +2 and +3, of which +3 by far prevails. The inner coordination spheres about the Fe(0) atom are tetrahedral (FeC4) or sandwiched (FeC10), Fe(II) atoms are six-coordinated, and Fe(III) are six or even seven-coordinated. The inner coordination about M atoms range from four- through six- to eight-coordinated. The shortest Fe-Fe, Fe-M (transition) and Fe-M (lanthanide) and M-M separations are: 8.08 Å, 3.033 Å for Fe-Cu, 3.010 Å for Fe-Yb and 2.505 Å for Mo-Mo.
Słowa kluczowe
Wydawca

Czasopismo
Rocznik
Tom
9
Numer
5
Strony
776-789
Opis fizyczny
Daty
wydano
2011-10-01
online
2011-07-24
Twórcy
autor
  • Department of Inorganic Chemistry, Slovak Technical University, Radlinskeho 9, 812 37, Bratislava, Slovak Republic, qmelnik@stuba.sk
autor
  • Department of Inorganic Chemistry, Slovak Technical University, Radlinskeho 9, 812 37, Bratislava, Slovak Republic
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-011-0067-x
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