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Czasopismo
2010 | 8 | 6 | 1185-1191
Tytuł artykułu

Extraction of trace acetylspiramycin in real aqueous environments using aqueous two-phase system of ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate and phosphate

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The partitioning of acetylspiramycin was carried out in an aqueous two-phase system (ATPS) formed by a hydrophilic ionic liquid (1-butyl-3-methylimidazolium tetrafluoraborate, [Bmim]BF4) and NaH2PO4. This ATPS is a simple, non-toxic and effective sample pretreatment technique, which was developed for the simultaneous separation, enrichment and rapid analysis of acetylspiramycin coupled with molecular fluorescence spectrophotometry. Analysis of the liquid-liquid equilibrium of [Bmim]BF4-salt ATPS demonstrated that the salting-out ability of different salts may be related to the Gibbs energy of hydration of the ions. The effects of types of salts, concentration of NaH2PO4, and temperature were analysed. Under optimum conditions, the average extraction efficiency and partition coefficient were 90.14% and 91.1, respectively. Thermodynamic functions provide some information about the molecular mechanism involved in acetylspiramycin transfer to the top phase, suggesting an important acetylspiramycin-[Bmim]BF4 interaction. The method yielded a linear range in the concentration from 1.0 to 10.0 µg mL−1 of acetylspiramycin, and the limit of detection was 0.02 µg mL−1. This method could be successfully applied for the analysis of acetylspiramycin in lake water, river water and groundwater. The proposed extraction technique appears to be suitable as a first step for the separation of macrolide antibiotics from real aqueous environments.
Wydawca

Czasopismo
Rocznik
Tom
8
Numer
6
Strony
1185-1191
Opis fizyczny
Daty
wydano
2010-12-01
online
2010-10-08
Twórcy
autor
  • School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P.R. China, yunwang@ujs.edu.cn
autor
  • School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P.R. China
autor
  • School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P.R. China
  • School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P.R. China
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-010-0080-5
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