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2010 | 8 | 4 | 797-805
Tytuł artykułu

Kinetics of base hydrolysis of α-amino acid esters catalyzed by palladium(II) piperazine complex

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The kinetics of base hydrolysis of glycine, histidine, and methionine methyl esters in the presence of [Pd(pip)(H2O)2]2+ complex, where pip is piperazine, is studied in aqueous solutions, at T = 25°C, and I = 0.1 mol dm−3. The rate of ester hydrolysis for glycine methyl ester is studied at different temperature and dioxane/water solutions of different compositions. The kinetic data are fit under the assumption that the hydrolysis proceeds in one step. The activation parameters for the base hydrolysis of the complexes are evaluated [...]
Wydawca

Czasopismo
Rocznik
Tom
8
Numer
4
Strony
797-805
Opis fizyczny
Daty
wydano
2010-08-01
online
2010-06-17
Twórcy
autor
  • Department of Chemistry, Faculty of Science, Cairo University, 12613, Giza, Egypt
  • Department of Chemistry, Faculty of Science, Cairo University, 12613, Giza, Egypt
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-010-0047-6
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