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2010 | 8 | 3 | 508-512
Tytuł artykułu

Phenylcopper(I) clusters in the gas phase obtained by laser desorption/ionization from bis(dibenzoylmethane)copper(II)

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
It has been demonstrated that phenylcopper(I)-containing clusters are generated in the gas phase from bis(dibenzoylmethane) copper(II) (Cu(dbm)2) by laser desorption/ ionization (LDI) method. For example, the [Cu5dbm2(C6H5)2]+ ion can be considered as consisting of two Cudbm molecules, two CuC6H5 molecules and a Cu+ cation. The [Cu5(C6H5)4]+ ion can be considered as phenylcopper(I) cluster (consisting of four phenylcopper molecules) ionized by additional Cu+ cation. Results from MS/MS (tandem mass spectrometry) experiments have confirmed the presence of phenylcopper molecules in the analyzed clusters. Ease of preparation of dibenzoylmethane-metal complexes and straightforward method to obtain LDI mass spectra offer a wide range of possibilities to study similar organometallic clusters in the gas phase. [...]
Wydawca

Czasopismo
Rocznik
Tom
8
Numer
3
Strony
508-512
Opis fizyczny
Daty
wydano
2010-06-01
online
2010-04-25
Twórcy
autor
  • Faculty of Chemistry, Adam Mickiewicz University, 60-780, Poznań, Poland
  • Faculty of Chemistry, Adam Mickiewicz University, 60-780, Poznań, Poland
  • Faculty of Chemistry, Adam Mickiewicz University, 60-780, Poznań, Poland
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-010-0017-z
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