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2010 | 8 | 2 | 396-408
Tytuł artykułu

Ion-exchange studies on poly-o-anisidine Sn(IV) phosphate nano composite and its application as Cd(II) ion-selective membrane electrode

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Treść / Zawartość
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Języki publikacji
EN
Abstrakty
EN
An organic-inorganic composite, poly-o-anisidine Sn(IV) phosphate, was chemically synthesized by mixing ortho-anisidine into gels of Sn(IV) phosphate with different mixing volume ratios. Studies on the effect of eluant concentration, elution behavior and separation of metal ions were carried out to understand the ion-exchange capabilities. Due to Cd(II) selective nature of composite, revealed by distribution studies, Cd(II) ion selective membrane electrode was fabricated. The analytical utility of the electrode was established by employing it as an indicator electrode in electrometric titrations having fast response time, 3–5s, and long life span of six months. Some physical parameters like self-diffusion coefficient (D0), activation energy (Ea) and entropy of activation (ΔS0) have been evaluated under conditions favoring a particle diffusion-controlled mechanism by studying ion-exchange kinetics. [...]
Wydawca

Czasopismo
Rocznik
Tom
8
Numer
2
Strony
396-408
Opis fizyczny
Daty
wydano
2010-04-01
online
2010-03-23
Twórcy
autor
  • Analytical and Polymer Research Laboratory, Department of Applied Chemistry, Faculty of Engineering and Technology, Aligarh Muslim University, Aligarh, 202002, India, asifkhan42003@yahoo.com
autor
  • Analytical and Polymer Research Laboratory, Department of Applied Chemistry, Faculty of Engineering and Technology, Aligarh Muslim University, Aligarh, 202002, India, anishkhan97@gmail.com
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-010-0002-6
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