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2010 | 8 | 1 | 1-11
Tytuł artykułu

Catalytic activity of thiourea and its selected derivatives on electroreduction of In(III) in chlorates(VII)

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
It was found that thiourea, N-methylthiourea, N,N′-dimethylthiourea and N-allylthiourea accelerate the electroreduction process of In(III) ions in chlorates(VII). These substances are adsorbed on mercury from chlorates(VII). The relative surface excesses of thiourea and its derivatives increase with the increase of their concentrations and electrode charge. After adding thiourea, N-methylthiourea, N,N′-dimethylthiourea and N-allylthiourea to the solution an acceleration of the electroreduction process of In(III) ions occurs. This process depends on two factors: the adsorption of an accelerating substance on mercury and on the formation of complexes between a depolarizer and an accelerating substance on the electrode surface. The equilibrium of this complexing reaction determines the magnitude of the catalytic effect. [...]
Wydawca

Czasopismo
Rocznik
Tom
8
Numer
1
Strony
1-11
Opis fizyczny
Daty
wydano
2010-02-01
online
2010-02-16
Twórcy
Bibliografia
  • [1] M.T. Ludwik, Indium (Indium. Corp. of America, New York, 1959)
  • [2] J.C. Lin, H.C. Shih, J. Electrochem. Soc. 134, 817 (1987) http://dx.doi.org/10.1149/1.2100578[Crossref]
  • [3] M.A. Filyand, E.J. Semenova, Handbook of the Rare Elements (MacDonald, London, 1969)
  • [4] J.H. de Bussy, T.J.W. van Thoor (Eds.), Metals and Ores (Longman, London, 1970) vol. 3
  • [5] J. Strang, Dental materials 3, 26 (1998)
  • [6] Y. Shigesato, S. Takaki, T. Haranoh, J. Appl. Phys. 71, 3356 (1992) http://dx.doi.org/10.1063/1.350931[Crossref]
  • [7] J.I. Jeong, J.H. Moon, J.H. Hong, J.S. Kang, Y.P. Lee, Appl. Phys. Lett. 64, 1215 (1994) http://dx.doi.org/10.1063/1.110893[Crossref]
  • [8] A. Manisingh, C.V.R. Vasant Kumar, J. Phys. D 22, 455 (1989) http://dx.doi.org/10.1088/0022-3727/22/3/013[Crossref]
  • [9] S. Omanovic, M. Metikos-Hukovic, Thin Solid Films 458, 52 (2004) http://dx.doi.org/10.1016/j.tsf.2003.11.271[Crossref]
  • [10] K. Nishiyama, H. Ishida, I. Taniguchi, J. Electroanal. Chem. 373, 255 (1994) http://dx.doi.org/10.1016/0022-0728(94)03528-8[Crossref]
  • [11] Z. Salamon, G. Tollin, Photochem. Photobiol. 58, 730 (1993) http://dx.doi.org/10.1111/j.1751-1097.1993.tb04960.x[Crossref]
  • [12] M. Tominaga, T. Kumagai, S. Takita, I. Taniguchi, Chem. Lett. 10, 1771 (1993) http://dx.doi.org/10.1246/cl.1993.1771[Crossref]
  • [13] I. Taniguchi, Y. Mie, K. Nishiyama, V. Brabec, O. Novakova, S. Neya, N. Funasaki, J. Electroanal. Chem. 420, 5 (1997) http://dx.doi.org/10.1016/S0022-0728(96)01022-4[Crossref]
  • [14] A.I. Molodov, V.V. Losev, Elektrokhimiya 1,1253 651 (1965)
  • [15] J.G. Lawson, D.A. Aikens, J. Electroanal. Chem. 15, 193 (1967) http://dx.doi.org/10.1016/0022-0728(67)85023-X[Crossref]
  • [16] R.D. Armstrong, A.B. Suttie, H.R Thirsk, Electrochem. Acta 13, 1 (1968) http://dx.doi.org/10.1016/0013-4686(68)80001-5[Crossref]
  • [17] J.I. Turyan, N.K. Strizhow, Elektrokhimiya 11, 458 (1975)
  • [18] G. Biedermann, T. Wallin, Acta Chem. Scand. 14, 594 (1960). http://dx.doi.org/10.3891/acta.chem.scand.14-0594[Crossref]
  • [19] F.J.C. Rossotti, H. Rossotti, Acta Chem. Scand. 10, 779 (1956) http://dx.doi.org/10.3891/acta.chem.scand.10-0779[Crossref]
  • [20] A. Aziz, J.S. Lyle, J. Inorg. Nucl. Chem. 31, 2431 (1969) http://dx.doi.org/10.1016/0022-1902(69)80575-0[Crossref]
  • [21] P. Hemmes, L.D. Rich, D.L. Cole, E.M. Eyring, J. Phys. Chem. 74, 2859 (1970) http://dx.doi.org/10.1021/j100709a001[Crossref]
  • [22] T.H. Cannon, R.E. Richards, Trans. Faraday Soc. 62, 1378 (1966) http://dx.doi.org/10.1039/tf9666201378[Crossref]
  • [23] A. Fratiello, R.E. Lee, V.M. Nishida, R.E. Schuster, J. Phys. 48, 3705 (1968)
  • [24] J. Celeda, D.G. Tuck, J. Inorg. Nucl. Chem. 36, 373 (1974) http://dx.doi.org/10.1016/0022-1902(74)80026-6[Crossref]
  • [25] M. Maeda, H. Ohtaki, Bull Chem. Soc. Jpn. 50, 1893 (1977) http://dx.doi.org/10.1246/bcsj.50.1893[Crossref]
  • [26] M. Eigen, Ber. Bunsenges. Phys. Chem. 67, 753 (1963) [Crossref]
  • [27] M. Eigen, Pure Appl. Chem. 6, 97 (1963) http://dx.doi.org/10.1351/pac196306010097[Crossref]
  • [28] E.M. Eyring, J.D. Owen, J. Phys. Chem. 74, 1825 (1970) http://dx.doi.org/10.1021/j100704a001[Crossref]
  • [29] M. ZeliĆ, M. Mlakar, M. Branica, Anal. Chim. Acta. 289, 299 (1994) http://dx.doi.org/10.1016/0003-2670(94)90005-U[Crossref]
  • [30] M.C. Montemayor, E. Fatas, Electrochim. Acta 33, 655 (1988) http://dx.doi.org/10.1016/0013-4686(88)80064-1[Crossref]
  • [31] R.R. Nazmutdinov, M.S. Shapnik, O.I. Malyucheva, Elektrokhimiya 29, 331 (1993)
  • [32] K. Sykut, G. Dalmata, B. Nowicka, J. Saba, J. Electroanal. Chem. 90, 299 (1978) http://dx.doi.org/10.1016/S0022-0728(78)80065-5[Crossref]
  • [33] A. Nosal-Wiercińska, Z. Fekner, G. Dalmata, J. Electroanal. Chem. 584, 192 (2005) http://dx.doi.org/10.1016/j.jelechem.2005.01.044[Crossref]
  • [34] A. Nosal-Wiercińska, G. Dalmata, Electrochim. Acta 51, 6179 (2006) http://dx.doi.org/10.1016/j.electacta.2006.01.062[Crossref]
  • [35] G. Dalmata, A. Nosal-Wiercińska, Croat. Chem. Acta 81, 529 (2008)
  • [36] J. Koryta, J. Dvorak, V. Bohackova, Elektrochemia (PWN, Warszawa, 1980) (In Polish)
  • [37] R. Parsons, R. Payne, Z. Phys. Chem. N. F. 98, 9 (1975)
  • [38] D.C. Grahame, R.P. Larsen, M.A. Poth, J. Am. Chem. Soc. 71, 2978 (1949) http://dx.doi.org/10.1021/ja01177a010[Crossref]
  • [39] D.C. Grahame, E.M. Coffin, J.J. Commings, M.A. Poth, J. Am. Chem. Soc. 74, 1207 (1952) http://dx.doi.org/10.1021/ja01125a021[Crossref]
  • [40] D.J. Schiffrin, J. Electroanal. Chem. 23, 168 (1969) http://dx.doi.org/10.1016/S0022-0728(69)80203-2[Crossref]
  • [41] R. Parsons, Trans. Faraday Soc. 51, 1518 (1955) http://dx.doi.org/10.1039/tf9555101518[Crossref]
  • [42] R. Parsons, Proc. Roy. Soc. A 261, 79 (1961) http://dx.doi.org/10.1098/rspa.1961.0062[Crossref]
  • [43] W.F. Schapink, M. Qudeman, K.W. Leu, J.N. Helle, Trans. Faraday Soc. Ser. A 56, 415 (1960) http://dx.doi.org/10.1039/tf9605600415[Crossref]
  • [44] R.R. Nazmutdinov, T.T. Zinkicheva, G.A. Tsirlina, Z.V. Kuz’minova, Electrochim. Acta 50, 4888 (2005) http://dx.doi.org/10.1016/j.electacta.2005.02.091[Crossref]
  • [45] A. Nosal-Wiercińska, G. Dalmata, Electroanalysis 14, 1275 (2002) http://dx.doi.org/10.1002/1521-4109(200210)14:18<1275::AID-ELAN1275>3.0.CO;2-P[Crossref]
  • [46] A. Nosal-Wiercińska, G. Dalmata, Polish J. Chem. 82, 1473 (2008).
  • [47] Southampton Electrochemistry Group, Instrumental Methods in Electrochemistry (The Ellis Horwood Ltd, Chichester, 1990) 190
  • [48] R.S. Nicholson, J. Shain, Anal. Chem. 36, 706 (1964) http://dx.doi.org/10.1021/ac60210a007[Crossref]
  • [49] R.S. Nicholson, Anal. Chem. 37, 1351 (1965) http://dx.doi.org/10.1021/ac60230a016[Crossref]
  • [50] A. Barański, S. Fitak, Z. Galus, J. Electroanal. Chem. 60, 175 (1975) http://dx.doi.org/10.1016/S0022-0728(75)80329-9[Crossref]
  • [51] D.C. Grahame, J. Am. Chem. Soc. 80, 4261 (1958) http://dx.doi.org/10.1021/ja01549a022[Crossref]
  • [52] Z. Galus, The Theoretical Basics of Chemical Electroanalysis (PWN, Warsaw, 1977) (in Polish)
  • [53] J.E.B. Randles, Trans Faraday Soc. 44, 327 (1948) http://dx.doi.org/10.1039/tf9484400327[Crossref]
  • [54] A. Ševčik, Coll. Czechoslov. Chem. Commun. 13, 349 (1948) [Crossref]
  • [55] J.E.B. Randles, In: P. Zumana (Ed.), Progress in Polarography (Interscience Publ., New York, 1962) 1, 123
  • [56] Z. Galus, Electroanalytical Methods of Determination of Physicochemical Constants (PWN, Warsaw, 1979) (in Polish)
  • [57] H. Matsuda, Y. Ayabe, Z. Elektrochem. 59, 494 (1955)
  • [58] O.A. Petrii, R.R. Nazmutdinov, M.D. Bronshtein, G.A. Tsirlina, Electrochim. Acta 52, 3493 (2007). http://dx.doi.org/10.1016/j.electacta.2006.10.014[Crossref]
  • [59] D.S. Turnham, J. Electroanal. Chem. 10, 19 (1965) http://dx.doi.org/10.1016/0022-0728(65)85011-2[Crossref]
  • [60] R. Tamamushi, K. Ishibashi, N. Tanaka, Z. Phys. Chem. N. F. 35, 209 (1962)
  • [61] G. Dalmata, Electroanalysis 17, 789 (2005) http://dx.doi.org/10.1002/elan.200403154[Crossref]
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-009-0109-9
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