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2009 | 7 | 4 | 731-738
Tytuł artykułu

The study of cyclooctene oxidation with molecular oxygen catalyzed by VSi2

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The catalytic effect of VSi2 on initial stages of the liquid-phase oxidation of cyclooctene by molecular oxygen was studied. The vanadium disilicide influences on the oxidation process in the presence of hydroperoxide. VSi2 takes part in a radical formation stage by catalysis of hydroperoxide decomposition reaction. The catalyst was investigated before and after reaction using FTIR spectroscopy. From the data obtained, the kinetic model of the catalytic oxidation process was proposed and the equation for the reaction rate was derived. The equation has described all observed dependences of reaction rate on the concentration of reactants and content of catalyst. [...]
Słowa kluczowe
Wydawca

Czasopismo
Rocznik
Tom
7
Numer
4
Strony
731-738
Opis fizyczny
Daty
wydano
2009-12-01
online
2009-10-06
Twórcy
  • Institute of Chemistry and Chemical Technologies, Lviv Polytechnic National University, 79013, Lviv, Ukraine, o_makota@polynet.lviv.ua
autor
  • Institute of Chemistry and Chemical Technologies, Lviv Polytechnic National University, 79013, Lviv, Ukraine
autor
  • Faculty of Chemistry, Maria Curie-Sklodowska University, 20-031, Lublin, Poland
  • Faculty of Chemistry, Maria Curie-Sklodowska University, 20-031, Lublin, Poland
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-009-0096-x
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