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Czasopismo
2009 | 7 | 3 | 291-297
Tytuł artykułu

Determination of Alizarin Red S using a novel B-Z oscillation system catalyzed by a tetraazamacrocyclic complex

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
A new and convenient method for the determination of Alizarin Red S by the perturbations caused by different amounts of Alizarin Red S on a novel B-Z oscillating system is proposed. This new type Belousov-Zhabotinskii involves a macrocyclic copper(II) complex [CuL](ClO4)2 as catalyst and malic acid as the substrate. The ligand L in the complex is 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene. It is found that the relationship between the change in the oscillation amplitude and the logarithm of the Alizarin Red S concentration in the range of 1.5 × 10−7 to 1 × 10−3 M fits a polynomial model: ΔA = 659 + 184.2 log [Alizarin Red S]+ 12.9 log2 [Alizarin Red S]. The RSD obtained with ten samples is 4.4%. The probable mechanism involving the perturbation of Alizarin Red S on the oscillating chemical system is also discussed. [...]
Wydawca

Czasopismo
Rocznik
Tom
7
Numer
3
Strony
291-297
Opis fizyczny
Daty
wydano
2009-09-01
online
2009-06-21
Twórcy
autor
  • Department of Chemistry, Anhui University, Hefei, 230039, P. R. China, hugang@ustc.edu
autor
  • Department of Chemistry, Anhui University, Hefei, 230039, P. R. China
  • Department of Chemistry, Anhui University, Hefei, 230039, P. R. China
autor
  • Department of Chemistry, Anhui University, Hefei, 230039, P. R. China
autor
  • Department of Chemistry, Anhui University, Hefei, 230039, P. R. China
autor
  • Department of Chemistry, Anhui University, Hefei, 230039, P. R. China
  • Department of Chemistry, Anhui University, Hefei, 230039, P. R. China
autor
  • Department of Chemistry, Anhui University, Hefei, 230039, P. R. China
autor
  • Institute of Applied Chemistry, East China Jiaotong University, Nanchang, 330013, P. R. China
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-009-0042-y
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