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Czasopismo
2008 | 6 | 3 | 419-428
Tytuł artykułu

Kinetic studies for the esterification of acetic acid with epichlorohydrin over an anion exchange resin catalyst

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The kinetics of the esterification reaction between acetic acid and epichlorohydrin catalysed by Purolite A-520E strong basic anion exchange resin was studied. The effects of certain parameters such as stirring speed, particle diameter, temperature, catalyst amount and molar ratio between reactants were experimentally determined. It was found that the overall reaction rate is intrinsically kinetically controlled. The partial orders of reaction with respect to catalyst, acetic acid and epichlorohydrin were determined. A reaction mechanism is proposed. Based on chromatographic data and taking into account the partial orders of reaction, a more detailed kinetic model is suggested. [...]
Wydawca

Czasopismo
Rocznik
Tom
6
Numer
3
Strony
419-428
Opis fizyczny
Daty
wydano
2008-09-01
online
2008-08-11
Twórcy
autor
  • Departement of Organical and Biochemical Engineering, The Faculty of Chemical Engineering, “Gh. Asachi” Technical University of Iassy, D. Mangeron Street, Iasi, 700050, Romania, eimuresan@yahoo.co.uk
  • Departement of Organical and Biochemical Engineering, The Faculty of Chemical Engineering, “Gh. Asachi” Technical University of Iassy, D. Mangeron Street, Iasi, 700050, Romania
autor
  • Ecole Nationale Superieure de Chimie de Montpellier 8, rue de l’Ecole Normale, Montpellier, Cedex, 5, France
  • Departament of Natural and Synthetic Polymers, The Faculty of Chemical Engineering, “Gh. Asachi” Technical University of Iassy, D. Mangeron street, 71A, Iasi, 700050, Romania
autor
  • Departament of Natural and Synthetic Polymers, The Faculty of Chemical Engineering, “Gh. Asachi” Technical University of Iassy, D. Mangeron street, 71A, Iasi, 700050, Romania
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-008-0046-z
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