Can N-heterocyclic germylenes behave as Lewis acids - is there another side to Meller germylenes?

• Autorzy: Olaf Kühl
• Języki publikacji: EN

Abstrakty

EN

N-Heterocyclic germylenes are known to exist in two structurally different forms, the planar Meller germylenes and the monoimino germylenes that feature an envelope structure. This essay reviews recent reports dealing with radical and cationic Meller type germylenes featuring the monoimino germylene structure, discusses their transformations and relationships, and asks the question whether indeed N-heterocyclic germylenes can be turned into Lewis acids. [...]

Słowa kluczowe

EN

Carbene Homologues; Germylenes; Electron-deficient Compounds; Electronic Structure; Germanium; Heterocycles; Ligand Design; Main Group Elements; Substituent Effects

• Czasopismo: Open Chemistry
• Rocznik: 2008
• Tom: 6
• Numer: 3
• Strony: 365-372

Daty

wydano

2008-09-01

online

2008-08-11

Twórcy

autor

Olaf Kühl

• Institut für Biochemie, EMA Universität Greifswald, D-17489, Greifswald, Germany,

Bibliografia

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Identyfikatory

DOI

10.2478/s11532-008-0040-5